
|
Product Name |
RXSOL-60-6605-722 |
|
Product Type |
THIOUREA PURIFIED |
|
Revised date |
|
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Chennai, Visakhapatnam, Kolkata, Fujairah, Muscat Barka
|
Phone |
+91 22 27815541 / 42 |
|
Fax |
+91 22 2781 1318 :::AOH :0091 9821214367 |
|
Email |
mail@rxmarine.com |

Substance / Preparation : Thiourea
CAS No :62-56-6
Substance name Contents CAS No
Thiourea : 100 % 62-56-6
Substance.
Contains no other components or impurities which will influence the classification of the
product.
3.1. Classification of the substance or mixture
Classification EC 67/548 or EC 1999/45
Classification : Carc. Cat. 3; R40
Repr. Cat. 3; R63
Xn; R22
N; R51-53
Hazard Class and Category Code(s), Regulation (EC) No 1272/2008 (CLP)
Health hazards : Carcinogenicity - Category 2 - Warning (CLP : Carc. 2) H351
Reproductive toxicity - Unborn Child - Category 2 - Warning (CLP : Repr. 2) H361
Acute toxicity, Oral - Category 4 - Warning (CLP : Acute Tox. 4) H302
Environmental hazards : Hazardous to the aquatic environment - Chronic hazard-
Category 2 (CLP : Aquatic Chronic 2) H411
3.2. Label elements
Labelling EC 67/548 or EC 1999/45
Symbol(s) : Xn : Harmful
N : Dangerous for the environment
R Phrase(s) : R63 : Possible risk of harm to the unborn child.
R22 : Harmful if swallowed.
R40 : Limited evidence of a carcinogenic effect.
R51/53 : Toxic to aquatic organisms, may cause long-term adverse effects in the
aquatic environment.
R63: Possible risk of harm to the unborn child.
S Phrase(s) : S36/37 : Wear suitable protective clothing and gloves.
S61 : Avoid release to the environment. Refer to special instructions/Safety data sheets.
Labelling Regulation EC 1272/2008 (CLP)
Hazard pictograms
Signal words : Warning
Hazard statements : H351 : Suspected of causing cancer.
H302 : Harmful if swallowed.
H411 : Toxic to aquatic life with long lasting effects.
H361d: Suspected of damaging the unborn child.
Precautionary statements
• General : P201: Obtain special instructions before use.
• Prevention : P281: Use personal protective equipment as required.
P273: Avoid release to the environment.
P264: Wash thoroughly after handling.
P270: Do not eat, drink or smoke when using this product.
• Response : P301+P312: IF SWALLOWED : Call a POISON CENTER or doctor if you
feel unwell.
P308+P313: If exposed or concerned : get medical advice.
P391: Collect spillage.
• Storage : P405: Store locked up.
• Disposal considerations : P501: Dispose of this material and its container to hazardous
or special waste collection point, in accordance with local, regional, national and/or
international regulation.
3.3. Other hazards
Other hazards : The substance does not fulfil the criteria to be identified as PBT
substance or vPvB substance according to Annex XIII of Regulation REACH.
4.1. Description of first aid measures
Inhalation : Assure fresh air breathing. Allow the victim to rest.
Skin contact : Remove affected clothing and wash all exposed skin area with mild soap
and water, followed by warm water rinse.
Eye contact : Rinse immediately with plenty of water. Obtain medical attention if pain,
blinking or redness persist.
Ingestion : Obtain emergency medical attention. Rinse mouth. Call a POISON CENTER
or doctor if you feel unwell. Do NOT induce vomiting.
4.2. Most important symptoms and effects, both acute and delayed
Symptoms relating to use : Swallowing a small quantity of this material will result in
serious health hazard. Suspected of causing cancer. Suspected of damaging the unborn
child.
4.3. Indication of any immediate medical attention and special treatment needed
General information : Never give anything by mouth to an unconscious person.
If exposed or concerned : get medical advice.
5.1. Extinguishing media
Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand.
Unsuitable extinguishing media : Do not use a heavy water stream.
Surrounding fires : Use water spray or fog for cooling exposed containers.
5.2. Special hazards arising from the substance or mixture
Hazardous combustion products : Under fire conditions, hazardous fumes will be
present.
5.3. Advice for fire-fighters
Protection against fire : Do not enter fire area without proper protective equipment,
including respiratory protection.
Special procedures : Exercise caution when fighting any chemical fire. Avoid (reject)
fire-fighting water to enter environment.
6.1. Personal precautions, protective equipment and emergency procedures
For emergency responders : Equip cleanup crew with proper protection.
Ventilate area.
For non-emergency personnel : Evacuate unnecessary personnel.
6.2. Environmental precautions
Environmental precautions : Prevent entry to sewers and public waters. Notify
authorities if product enters sewers or public waters. Avoid release to the environment.
6.3. Methods and material for containment and cleaning up
Clean up methods : On land, sweep or shovel into suitable containers. Minimize
generation of dust. Store away from other materials.
6.4. Reference to other sections
See section 8. Exposure controls/personal protection
7.1. Precautions for safe handling
Handling : Wash thoroughly after handling. Do not eat, drink or smoke when using this
product. Obtain special instructions before use.
Technical protective measures : Provide good ventilation in process area to prevent
formation of vapour.
7.2. Conditions for safe storage, including any incompatibilities
Storage : Keep only in the original container in a cool, well ventilated place. Keep
container closed when not in use.
Storage - away from : Strong bases. Strong acids. Sources of ignition. Direct sunlight.
7.3. Specific end use(s)
Specific end use(s) : None.
8.1. Exposure controls
Personal protection : Avoid all unnecessary exposure.
• Respiratory protection : Wear approved mask.
• Hand protection : Wear protective gloves.
• Eye protection : Chemical goggles or safety glasses.
• Others : When using, do not eat, drink or smoke.
8.2. Control parameters
Occupational Exposure Limits : No data available.
9.1. Information on basic physical and chemical properties
Physical state at 20 °C : Solid.
Odour threshold : No data available.
pH value : Not applicable
.Melting point [°C] : 170 - 176 °C
Decomposition point [°C] : N/A
Critical temperature [°C] : N/A
Auto-ignition temperature [°C] : N/A
Flammability (solid, gas) : N/A
Flash point [°C] : N/A
Boiling point [°C] : N/A
Initial boiling point [°C] : N/A
Final boiling point [°C] : N/A
Evaporation rate : N/A
Vapour pressure [20°C] : N/A
Vapour pressure mm/Hg : N/A
Vapour density : N/A
Density [g/cm3] : 1,045
Relative density, gas (air=1) : N/A
Relative density, liquid (water=1) : N/A
Solubility in water [% weight] : 137 g/l at 20 °C
Solubility in water : N/A
Log Pow octanol / water at 20°C : No data available.
Solubility : 5 - 7
Viscosity at 40°C [mm2/s] : N/A
9.2. Other information
Explosive properties : N/A
Explosion limits - upper [%] : N/A
Explosion limits - lower [%] : N/A
Oxidising properties : No data available
10.1. Reactivity
Reactivity : Not established.
10.2. Chemical stability
Chemical stability : Stable under recommended storage conditions.
10.3. Possibility of hazardous reactions
Hazardous reactions : Not established.
10.4. Conditions to avoid
Conditions to avoid : Direct sunlight. Extremely high or low temperatures.
10.5. Incompatible materials
Materials to avoid : Strong acids. Strong bases.
10.6. Hazardous decomposition products
Hazardous decomposition products : Fumes. Carbon monoxide. Carbon dioxide
11.1. Information on toxicological effects
Acute toxicity
• Inhalation : Based on available data, the classification criteria are not met.
• Dermal : Based on available data, the classification criteria are not met.
• Ingestion : Harmful if swallowed.
Corrosion : Based on available data, the classification criteria are not met.
Irritation : Based on available data, the classification criteria are not met.
Sensitization : Based on available data, the classification criteria are not met.
Mutagenicity : Based on available data, the classification criteria are not met.
Carcinogenicity : Suspected of causing cancer.
Toxic for reproduction : Suspected of damaging the unborn child.
STOT-single exposure : Based on available data, the classification criteria are not met.
STOT-repeated exposure : Based on available data, the classification criteria are not met.
Aspiration hazard : Based on available data, the classification criteria are not met.
12.1. Toxicity
Toxicity information : Toxic to aquatic life with long lasting effects.
12.2. Persistence - degradability
Persistence - degradability : May cause long-term adverse effects in the environment.
12.3. Bioaccumulative potential
Bioaccumulative potential : Not established.
12.4. Mobility in soil
Mobility in soil : Not established.
12.5. Results of PBT and vPvB assessment
Results of PBT and vPvB assessment : The substance does not fulfil the criteria to be
identified as PBT substance or vPvB substance according to Annex XIII of Regulation
REACH.
12.6. Other adverse effects
Environmental precautions : Avoid release to the environment.
13.1. Waste treatment methods
General : Avoid release to the environment. Dispose in a safe manner in accordance with
local/national regulations. Dispose of this material and its container to hazardous or
special waste collection point, in accordance with local, regional, national and/or
international regulation.

14.1. Land transport (ADR-RID)
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
H.I. nr : 90
ADR - Class : 9
Labelling - Transport : 9 : Miscellaneous dangerous substances and articles.
ADR - Classification code : M7
ADR - Group : III
ADR - Packing instructions : P002 R001 LP002
ADR - Limited Quantity : 5 KG
ADR - Tunnel code : E : Passage forbidden through tunnels of category E.
14.2. Sea transport (IMDG) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
IMO-IMDG - Class or division : 9 : Miscellaneous dangerous substances and articles.
IMO-IMDG - Packing group : III
IMO- IMDG - Packing instructions : P002 LP02
IMO-IMDG - Limited quantities : 5 kg
IMO-IMDG - Marine pollution : Yes
EMS-Nr : F-A S-F
14.3. Air transport (ICAO-IATA) [English only]
Proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE,
SOLID, N.O.S.
UN N° : 3077
IATA - Class or division : 9 : Miscellaneous dangerous substances and articles.
IATA - Packing group : III
IATA - Passenger and Cargo Aircraft : ALLOWED
- Passenger and Cargo - Packing : 956
instruction
- Passenger and Cargo - Maximum : 400 kg
Quantity/Packing
IATA - Cargo only : ALLOWED
- Cargo only - Packing instruction : 956
- Cargo only - Maximum Quantity/ : 400 kg
Packing IATA - Limited Quantites : 30 kg G
ERG-Nr : 9L
15.1. Safety, health and environmental regulations/legislation specific for the
substance or mixture
Safety, health and environmental : Ensure all national/local regulations are observed.
regulations/legislation specific for the substance or mixture
REACH
Restrictions - Annex XVII : The components of this product are not subject to
restrictions.
REACH Authorisation - Annex XIV : The components of this product are not subject
to authorization.
15.2. Chemical Safety Assessment
Chemical Safety Assessment : It has not been carried out
Abbreviations and acronyms : PBT: persistent, bioaccumulative and toxic.
vPvB: very persistent and very bioaccumulative
Sources of key data used : REGULATION (EC) No 1272/2008 OF THE EUROPEAN
PARLIAMENT AND OF THE COUNCIL of 16 December 2008 on classification,
labelling and packaging of substances and mixtures, amending and repealing Directives
67/548/EEC and 1999/45/EC, and amending Regulation (EC) No 1907/2006
Further information : None.
In accordance with REACH Regulation (CE) Nº 1907/2006 and with CLP Regulation
(CE) Nº 1272/2008 DISCLAIMER OF LIABILITY The information in this SDS was
obtained from sources which we believe are reliable. However, the information is
provided without any warranty, express or implied, regarding its correctness. The
conditions or methods of handling,storage, use or disposal of the product are beyond our
control and may be beyond our knowledge. For this and other reasons, we do not assume
responsibility and expressly disclaim liability for loss, damage or expense arising out of or
in any way connected with the handling, storage, use or disposal of the product. This
MSDS was prepared and is to be used only for this product. If the product is used as a
component in another product, this MSDS information may not be applicable.