
|
Porduct Name |
PH Controller Amine Based |
|
Part Number |
RXSOL-42-5024-210 |
Company Details:....
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
|
Phone |
+91 22 20871200 - 1400 |
|
Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
|
Email |
mail@rxmarine.com |
|
Website |
www.rxmraine.com |

Pure substance/mixture : Mixture
|
Chemical Name |
Cas No |
Concentration: (%) |
|
Monoethanolamine |
141-43-5 |
30 - 60 |
|
Methoxypropylamine |
5332-73-0 |
10 - 30 |

|
Signal Word |
Danger |
|
Hazard Statements |
Harmful if swallowed or if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction. May cause respiratory irritation. |
|
Precautionary statements |
Prevention:
Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. Wear protective gloves/ protective clothing/ eye protection/ face protection. Contaminated work clothing should not be allowed out of the workplace. Use only outdoors or in a well- ventilated area. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product.
Response:
IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/doctor. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If skin irritation or rash occurs: Get medical advice/ attention. Take off contaminated clothing and wash it before reuse.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store locked up.
Disposal:
Dispose of contents/ container to an approved waste disposal plant.
|
|
Other hazards |
None known. |

|
In case of eye contact |
Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention immediately. |
|
In case of skin contact |
Wash off immediately with plenty of water for at least 15 minutes. Use a mild soap if available. Wash clothing before reuse. Thoroughly clean shoes before reuse. Get medical attention immediately. |
|
If swallowed |
Rinse mouth with water. Do NOT induce vomiting. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
|
|
If inhaled |
Remove to fresh air. Treat symptomatically. Get medical attention. |
|
Protection of first-aiders |
In event of emergency assess the danger before taking action. Do not put yourself at risk of injury. If in doubt, contact emergency responders. Use personal protective equipment as required. |
|
Notes to physician |
Treat symptomatically. |
|
Most important symptoms and effects, both acute and delayed |
See Section 11 for more detailed information on health effects and symptoms. |

|
Suitable extinguishing media |
Use extinguishing measures that are appropriate to local circumstances and the
surrounding environment.
|
|
Unsuitable extinguishing media |
None known. |
Hazardous combustion
products |
Decomposition products may include the following materials: Carbon oxides nitrogen oxides (NOx)
|
|
Specific hazards during firefighting |
Not flammable or combustible. |
|
Special protective equipment for firefighters |
Use personal protective equipment. |
|
Specific extinguishing methods |
Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. In the event of fire and/or explosion do not breathe fumes. |

|
Personal precautions, protective equipment and emergency procedures |
Ensure adequate ventilation. Keep people away from and upwind of spill/leak. Avoid inhalation, ingestion and contact with skin and eyes. When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Ensure clean-up is conducted by trained personnel only. Refer to protective measures listed in sections 7 and 8. |
|
Enviromental Precaution |
Do not allow contact with soil, surface or ground water. |
Methods and materials for
containment and cleaning up |
Stop leak if safe to do so. Contain spillage, and then collect with non- combustible absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local / national regulations (see section 13). Flush away traces with water. For large spills, dike spilled material or otherwise contain material to ensure runoff does not reach a waterway. |
|
Reference to other sections |
For disposal see section 13. |

|
Advice on protection against fire and explosion |
Keep away from sources of ignition - No smoking.Take measures to prevent the build up of electrostatic charge. |
|
Incompatible materials |
Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills. |
|
Hygiene measures |
Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. For precautions see section 2.2. |
|
Advice on safe handling |
Avoid contact with skin and eyes. Avoid inhalation of vapor or mist. |
|
Conditions for safe storage, including any incompatibilities |
Tightly closed. Dry. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Moisture sensitive. |
|
Storage conditions |
Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store in cool place. |
|
Storage class |
Storage class (TRGS 510): 3: Flammable liquids |
|
Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
|
Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |

Components with workplace control parameters
Exposure guidelines have not been established for this product. Available exposure limits for the substance(s) are shown below.
|
Components |
CAS-No. |
Form of exposure |
Permissible
concentration |
Basis |
|
Monoethanolamine |
141-43-5 |
PEL (long term) |
3 ppm
7.5 mg/m3
|
SG PEL |
|
|
|
PEL (short term) |
6 ppm
15 mg/m3
|
SG PEL |
|
Monoethanolamine |
141-43-5 |
TWA |
3 ppm |
ACGIH |
|
|
|
STEL |
6 ppm |
ACGIH |
|
|
|
TWA |
3 ppm
8 mg/m3
|
NIOSH REL |
|
|
|
STEL |
6 ppm
15 mg/m3
|
NIOSH REL |
|
|
|
TWA |
3 ppm
6 mg/m3
|
OSHA Z1 |
Engineering measures : Effective exhaust ventilation system. Maintain air concentrations below occupational exposure standards.
Personal protective equipment
|
Eye protection |
Safety goggles Face-shield |
|
Hand protection |
Wear the following personal protective equipment:
Standard glove type.
Nitrile
butyl-rubber
Gloves should be discarded and replaced if there is any indication of
degradation or chemical breakthrough.
|
|
Skin protection |
Personal protective equipment comprising: suitable protective gloves, safety goggles and protective clothing |
|
Respiratory protection |
When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. |
|
Hygiene measures |
Handle in accordance with good industrial hygiene and safety practice. Remove and wash contaminated clothing before re-use. Wash face, hands and any exposed skin thoroughly after handling. Provide suitable facilities for quick drenching or flushing of the eyes and body in case of contact or splash hazard. |
The Personal Protective Equipment (PPE) recommendations provided above have been made in good faith based on typical expected conditions of use. PPE selection should always be completed in conjunction with a proper risk assessment and in accordance with a PPE management program.

|
Appearance |
Liquid |
|
Colour |
Light yellow |
|
Odour |
Amine-like |
|
Odor Threshold |
No data available |
|
pH |
11,(100 %), (25 °C) |
|
Melting point/freezing point |
POUR POINT: -34 °C |
|
Initial boiling point and boiling range |
> 100 °C |
|
Flash Point |
> 93.3 °C, Method: ASTM D 93, Pensky-Martens closed cup |
|
Evaporation Rate |
No data available |
|
Flammability (solid, gas) |
Not applicable |
|
Upper/lower explosive limits |
no data available |
|
Vapour pressure |
0.5 mm Hg, (37.8 °C), |
|
Viscosity |
No data available |
|
Density |
No data available |
|
Water solubility |
Completely soluble |
|
Solubility in other solvents |
No data available |
|
Partition coefficient: n- octanol/water |
No data available |
|
Auto-ignition temperature |
No data available |
|
Thermal decomposition |
No data available |
|
Viscosity, dynamic |
No data available |
|
Viscosity, kinematic |
11.3 mm2/s (38 °C) |
|
Molecular weight |
No data available |
|
VOC |
No data available |

|
Reactivity |
No dangerous reaction known under conditions of normal use. |
|
Chemical stability |
pressure build-up |
|
Possibility of hazardous reactions |
No dangerous reaction known under conditions of normal use. |
|
Conditions to avoid |
None known. |
|
Incompatible materials |
Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors. Contact with strong acids (e.g. sulfuric, phosphoric, nitric, hydrochloric, chromic,
sulfonic) may generate heat, splattering or boiling and toxic vapors. Avoid contact with SO2 or acidic bisulfite products, which may react to form visible airborne amine salt particles. Certain amines in contact with nitrous acid, organic or inorganic nitrites or atmospheres with high nitrous oxide concentrations may produce N- nitrosamines, many of which are cancer-causing agents to laboratory animals.
|
|
Hazardous decomposition products |
In case of fire, hazardous decomposition products may be produced such as:
Carbon oxides
nitrogen oxides (NOx)
|

|
Information on likely routes of exposure |
Inhalation, Eye contact, Skin contact |
Potential Health Effects
|
Eyes |
Causes serious eye damage. |
|
Skin |
Causes severe skin burns. May cause allergic skin reaction. |
|
Ingestion |
Harmful if swallowed. Causes digestive tract burns. |
|
Inhalation |
Harmful if inhaled. May cause respiratory irritation. May cause nose, throat, and lung irritation. |
|
Chronic Exposure |
Health injuries are not known or expected under normal use. |
Experience with human exposure
|
Eye contact |
Redness, Pain, Corrosion |
|
Skin contact |
Redness, Pain, Irritation, Corrosion, Allergic reactions |
|
Ingestion |
Corrosion, Abdominal pain, Vomiting |
|
Inhalation |
Respiratory irritation, Cough |
Toxicity
Product
|
Acute oral toxicity |
Acute toxicity estimate: 1,791 mg/kg |
|
Acute inhalation toxicity |
Acute toxicity estimate: 3.56 mg/l
Exposure time: 4 h
Test atmosphere: dust/mist
|
|
Acute dermal toxicity |
No data available |
|
Skin corrosion/irritation |
Species: Rabbit
Exposure time: 1 hrs
Result: Corrosive
Test substance: Product
Species: Rabbit
Exposure time: 1 hrs
Result: 2.0
Method: Oedema
Test substance: Product
Species: Rabbit
Exposure time: 1 hrs
Result: 4.0
Method: Erythema
Test substance: Product
|
|
Serious eye damage/eye irritation |
No data available |
|
Respiratory or skin sensitization |
Result: May cause an allergic skin reaction. |
|
Carcinogenicity |
No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. |
|
Reproductive effects |
No reproductive toxic effects expected. |
|
Germ cell mutagenicity |
Contains no ingredient listed as a mutagen |
|
Teratogenicity |
No data available |
|
STOT - single exposure |
May cause respiratory irritation. |
|
STOT - repeated exposure |
No data available |
|
Aspiration toxicity |
No aspiration toxicity classification |
Components
|
Acute dermal toxicity |
Monoethanolamine
LD50 rabbit: 1,025 mg/kg
Methoxypropylamine
LD50 rat: 2,000 mg/kg |
Human Hazard Characterization
Based on our hazard characterization, the potential human hazard is: High

Ecotoxicity
|
Environmental Effects |
Harmful to aquatic life with long lasting effects. |
Product
|
Toxicity to fish |
LC50 Pimephales promelas (fathead minnow): 1,046 mg/l
Exposure time: 96 hrs
Test substance: Product |
|
Toxicity to daphnia and other
aquatic invertebrates
|
LC50 Ceriodaphnia dubia: 141 mg/l
Exposure time: 48 hrs
Test substance: Product
|
|
Toxicity to algae |
No data available |
Components
|
Toxicity to algae |
Methoxypropylamine
EC50 : 31 mg/l
Exposure time: 72 h
|
Components
|
Toxicity to daphnia and other aquatic invertebrates
(Chronic toxicity)
|
Monoethanolamine
NOEC: 0.85 mg/l
Exposure time: 21 d
|
Persistence and degradability
|
The organic portion of this preparation is expected to be readily biodegradable. |
|
Chemical Oxygen Demand (COD): 800,000 mg/l |
Mobility
The environmental fate was estimated using a level III fugacity model embedded in the EPI (estimation program interface) Suite TM, provided by the US EPA. The model assumes a steady state condition between the total input and output. The level III model does not require equilibrium between the defined media. The information provided is intended to give the user a general estimate of the environmental fate of this product under the defined conditions of the models.
If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages;
|
Air |
5% |
|
Water |
10 - 30% |
|
Soil |
70 - 90% |
The portion in water is expected to be soluble or dispersible.
Bioaccumulative potential
This preparation or material is not expected to bioaccumulate.
Other information
No data available
ENVIRONMENTAL HAZARD AND EXPOSURE CHARACTERIZATION
Based on our hazard characterization, the potential environmental hazard is: Low

|
Disposal methods |
The product should not be allowed to enter drains, water courses or the soil. Where possible recycling is preferred to disposal or incineration. If recycling is not practicable, dispose of in compliance with local regulations. Dispose of wastes in an approved waste disposal facility. |
|
Disposal considerations |
Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. |

The shipper/consignor/sender is responsible to ensure that the packaging, labeling, and markings are in compliance with the selected mode of transport.
Land transport
|
UN/ID No. |
UN 2735 |
|
Proper shipping name |
AMINES, LIQUID, CORROSIVE, N.O.S. |
|
Technical name(s) |
Monoethanolamine, Methoxypropylamine |
|
Transport hazard class(es) |
8 |
|
Packing group |
II |
Air transport (IATA)
|
UN/ID No. |
UN 2735 |
|
Proper shipping name |
AMINES, LIQUID, CORROSIVE, N.O.S. |
|
Technical name(s) |
Monoethanolamine, Methoxypropylamine |
|
Transport hazard class(es) |
8 |
|
Packing group |
II
|
Sea transport (IMDG/IMO)
|
UN/ID No. |
UN 2735 |
|
Proper shipping name |
AMINES, LIQUID, CORROSIVE, N.O.S. |
|
Technical name(s) |
Monoethanolamine, Methoxypropylamine |
|
Transport hazard class(es) |
8 |
|
Packing group |
II |
|
Special precautions for user |
No special precautions required. |

APPLICABLE REGULATIONS, SINGAPORE
|
Chemical Weapons Prohibition Act |
|
Environmental Protection and Management Act |
|
Hazardous Waste Act |
|
Misuse of Drugs Act |
|
Strategic Goods Act |
|
Fire Safety (Petroleum and Flammable Materials) Regulations |
|
Not applicable. |
INTERNATIONAL CHEMICAL CONTROL LAWS :
|
United States TSCA Inventory |
|
The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710) |
|
Australia. Australian Industrial Chemicals Introduction Scheme (AICIS) |
|
All substances in this product comply with the Australian Industrial Chemicals Introduction Scheme (AICIS) |
|
Canadian Domestic Substances List (DSL) |
|
The substance(s) in this preparation are included in or exempted from the Domestic Substance List (DSL). |
|
Japan. ENCS - Existing and New Chemical Substances Inventory |
|
All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Existing and New Chemical Substances list (ENCS). |
|
Korea. Korean Existing Chemicals Inventory (KECI) |
|
All substances in this product comply with the Chemical Control Act (CCA) and are listed on the Existing Chemicals List (ECL) |
|
Philippines Inventory of Chemicals and Chemical Substances (PICCS) |
|
All substances in this product comply with the Republic Act 6969 (RA 6969) and are listed on the Philippines Inventory of Chemicals & Chemical Substances (PICCS). |
|
China Inventory of Existing Chemical Substances |
|
All substances in this product comply with the Provisions on the Environmental Administration of New Chemical Substances and are listed on or exempt from the Inventory of Existing Chemical Substances China (IECSC). |
|
Taiwan Chemical Substance Inventory |
|
All substances in this product comply with the Taiwan Existing Chemical Substances Inventory (ECSI). |
|
New Zealand. Inventory of Chemicals (NZIoC), as published by ERMA New Zealand |
|
All substances in this product comply with the Hazardous Substances and New Organisms (HSNO) Act 1996,and are listed on or are exempt from the New Zealand Inventory of Chemicals. |

|
Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.
|