|
Product Name |
RXSOL-22-2205-025 |
|
Product Type |
Muriatic Acid |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Gandhidham, Chennai, Visakhapatnam, Kolkata, Barka - Muscat, Fujairah, Nairobi, Canada
|
Phone |
+91 22 27815541 / 42 |
|
Fax |
+91 22 2781 1318 :::AOH :0091 9821214367 |
|
Email |
mail@rxmarine.com |
|
Ingredient
|
CAS No
|
Percent
|
Hazardous
|
|
Chlorous Acid
|
7647-01-0
|
32 - 38%
|
Yes
|
|
Water
|
7732-18-5
|
62 - 68%
|
No
|
Emergency Overview
DANGER! CORROSIVE. LIQUID AND MIST CAUSE SEVERE BURNS TO ALL BODY TISSUE. MAY BE FATAL IF SWALLOWED OR INHALED.
SAF-T-DATA(tm) Ratings (Provided here for your convenience)
|
Health Rating
|
3 - Severe (Poison)
|
|
Flammability Rating
|
0 - None
|
|
Reactivity Rating
|
1 - Slight
|
|
Contact Rating
|
4 - Extreme (Corrosive)
|
|
Lab Protective Equip
|
GOGGLES & SHIELD; LAB COAT & APRON; VENT HOOD; PROPER GLOVES
|
|
Storage Color Code
|
White (Corrosive)
|
Potential Health Effects Health hazards given on this data sheet apply to concentrated solutions of hydrochloric acid. Hazards of dilute solutions may be reduced, depending upon the concentration. Degree of hazard for these reduced concentrations is not currently addressed in the available literature.
|
Inhalation
|
Corrosive! Inhalation of vapors can cause coughing, choking, inflammation of the nose, throat, and upper respiratory tract, and in severe cases, pulmonary edema, circulatory failure, and death.
|
|
Ingestion
|
Corrosive! Swallowing hydrochloric acid can cause immediate pain and burns of the mouth, throat, esophagus and gastrointestinal tract. May cause nausea, vomiting, and diarrhea, and in severe cases, death.
|
|
Skin Contact
|
Corrosive! Can cause redness, pain, and severe skin burns. Concentrated solutions cause deep ulcers and discolor skin.
|
|
Eye Contact
|
Corrosive! Vapors are irritating and may cause damage to the eyes. Contact may cause severe burns and permanent eye damage.
|
|
Chronic Exposure
|
Long-term exposure to concentrated vapors may cause erosion of teeth. Long term exposures seldom occur due to the corrosive properties of the acid.
|
|
Aggravation of Pre-existing Conditions
|
Persons with pre-existing skin disorders or eye problems or impaired respiratory function may be more susceptible to the effects of the substance.
|
First aid procedures given apply to concentrated solutions. Exposures to dilute solutions may not require these extensive first aid procedures.
|
Inhalation
|
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical attention immediately.
|
|
Ingestion
|
If swallowed, DO NOT INDUCE VOMITING. Give large quantities of water. Never give anything by mouth to an unconscious person. Get medical attention immediately.
|
|
Skin Contact
|
Immediately flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Get medical attention immediately. Wash clothing before reuse. Thoroughly clean shoes before reuse.
|
|
Eye Contact
|
Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately.
|
|
Fire
|
Not considered to be a fire hazard. May react with metals or heat to release flammable hydrogen gas.
|
|
Explosion
|
Not considered to be an explosion hazard.
|
|
Fire Extinguishing Media
|
Water or water spray. Neutralize with soda ash or slaked lime.
|
|
Special Information
|
In the event of a fire, wear full protective clothing and NIOSH-approved self-contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. Structural firefighter's protective clothing is ineffective for fires involving hydrochloric acid. Stay away from ends of tanks. Cool tanks with water spray until well after fire is out.
|
Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible. Neutralize with alkaline material (soda ash, lime), then absorb with an inert material (e. g., vermiculite, dry sand, earth), and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! US Regulations (CERCLA) require reporting spills and releases to soil, water and air in excess of reportable quantities.
Store at room temperature. Store in a dry, ventilated storage area with acid resistant floors and good drainage. Protect from physical damage. Keep out of direct sunlight and away from heat and incompatible materials. Do not wash out container and use it for other purposes. When diluting, always add the acid to water; never add water to the acid. When opening metal containers, use non-sparking tools because of the possibility of hydrogen gas being present. Protect from freezing. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product.
|
Airborne Exposure Limits
|
|
For Hydrochloric acid
|
|
OSHA Permissible Exposure Limit (PEL)
|
5 ppm (Ceiling)
|
|
ACGIH Threshold Limit Value (TLV)
|
2 ppm (Ceiling), A4 Not classifiable as a human carcinogen
|
|
Ventilation System
|
A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details.
|
|
Personal Respirators (NIOSH Approved)
|
If the exposure limit is exceeded and engineering controls are not feasible, a full facepiece respirator with an acid gas cartridge may be worn up to 50 times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator
|
|
WARNING
|
Air purifying respirators do not protect workers in oxygen-deficient atmospheres.
|
|
Skin Protection
|
Rubber or neoprene gloves and additional protection including impervious boots, apron, or coveralls, as needed in areas of unusual exposure to prevent skin contact.
|
|
Eye Protection
|
Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area.
|
|
Appearance
|
Clear, colorless solution.
|
|
Odor
|
Pungent, hydrochloric acid.
|
|
Solubility
|
Infinitely soluble
|
|
Specific Gravity
|
ca. 1.3
|
|
pH
|
For solutions: 0.1 (1.0 N), 1.1 (0.1 N), 2.02 (0.01 N)
|
|
% Volatiles by volume @ 21C (70F)
|
100 (as water and acid)
|
|
Boiling Point
|
ca. 100C (ca. 212F)
|
|
Melting Point
|
ca. 0C (ca. 32F)
|
|
Vapor Density (Air=1)
|
Essentially the same as water.
|
|
Vapor Pressure (mm Hg)
|
Essentially the same as water.
|
|
Evaporation Rate (BuAc=1)
|
Essentially the same as water.
|
|
Stability
|
Stable under ordinary conditions of use and storage.
|
|
Hazardous Decomposition Products
|
When heated to decomposition, emits toxic hydrogen chloride fumes and will react with water or steam to produce heat and toxic and corrosive fumes. Thermal oxidative decomposition produces toxic chlorine fumes and explosive hydrogen gas.
|
|
Hazardous Polymerization
|
Will not occur
|
|
Incompatibilities
|
A strong mineral acid, concentrated hydrochloric acid is highly reactive with strong bases, metals, metal oxides, hydroxides, amines, carbonates and other alkaline materials. Incompatible with materials such as cyanides, sulfides, sulfites, and formaldehyde.
|
|
Conditions to Avoid
|
Heat, direct sunlight, incompatibles.
|
Muriatic acid: Inhalation rat LC50: 3124 ppm/1H; Oral rabbit LD50: 900 mg/kg. Investigated as a tumorigen, mutagen, reproductive effector. \Cancer Lists\-NTP Carcinogen Ingredient Known Anticipated ARC Category Hydrogen Chloride (7647-01-0) No No 3 Water (7732-18-5) - No -No-None
|
Environmental Fate
|
|
For Muriatic Acid (Concentrated Solutions)
|
When released into the soil, this material is not expected to biodegrade. When released into the soil, this material may leach into groundwater.
|
|
Environmental Toxicity
|
|
For Muriatic Acid (Concentrated Solutions)
|
This material may be toxic to aquatic life. LC50 Shrimp: 100-300 ppm/48-hr/salt water; LC100 trout: 10 mg/l/24-hr; TLm mosquito fish: 282 ppm/96-hr.
|
Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements.
|
Domestic (Land, D.O.T.) |
|
UN |
|
|
|
|
|
|
Proper Shipping Name |
HYDROGEN CHLORIDE SOLUTION |
|
|
|
|
UN NO. |
1789
|
|
|
|
|
Hazard Class |
8 |
Packing Group |
II |
|
|
Information reported for product/size |
210 L |
|
|
|
International (Water, I.M.O.)
|
|
|
Proper Shipping Name |
HYDROGEN CHLORIDE SOLUTION
|
|
|
|
|
UN No. |
1789
|
|
|
|
|
Hazard Class
|
8 |
Packing Group |
II
|
|
|
Information reported for product/size |
210L |
|
|
|
International (Air, I.C.A.O.)
|
|
|
Proper Shipping Name |
HYDROGEN CHLORIDE SOLUTION
|
|
|
|
|
UN No. |
1789
|
|
|
|
|
Hazard Class |
8 |
PackingGroup |
II
|
|
|
Information reported for product/size |
20L |
|
|
--------\Chemical Inventory Status - Part 1\---------------------------------
Ingredient TSCA EC Japan Australia
----------------------------------------------- ---- --- ----- ---------
Hydrogen Chloride (7647-01-0) Yes Yes Yes Yes
Water (7732-18-5) Yes Yes Yes Yes
--------\Chemical Inventory Status - Part 2\---------------------------------
--Canada--
Ingredient Korea DSL NDSL Phil.
----------------------------------------------- ----- --- ---- -----
Hydrogen Chloride (7647-01-0) Yes Yes No Yes
Water (7732-18-5) Yes Yes No Yes
--------\Federal, State & International Regulations - Part 1\----------------
-SARA 302- ------SARA 313------
Ingredient RQ TPQ List Chemical Catg.
----------------------------------------- --- ----- ---- --------------
Hydrogen Chloride (7647-01-0) 5000 500* Yes No
Water (7732-18-5) No No No No
--------\Federal, State & International Regulations - Part 2\----------------
-RCRA- -TSCA-
Ingredient CERCLA 261.33 8(d)
----------------------------------------- ------ ------ ------
Hydrogen Chloride (7647-01-0) 5000 No No
Water (7732-18-5) No No No
Chemical Weapons Convention: No TSCA 12(b): No CDTA: Yes
SARA 311/312: Acute: Yes Chronic: Yes Fire: No Pressure: No
Reactivity: No (Mixture / Liquid)
Australian Hazchem Code: None allocated.
Poison Schedule: None allocated.
WHMIS:
This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of
the information required by the CPR.
Text of R and S phrase codes used in this safety data sheet:- R34: Causes burns; R37: Irritating to respiratory system.The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties The data given here only applies when product used for proper application(s). The product is not sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.