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Product Name |
RXSOL-19-1363 |
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Product Type |
Methyl Acrylate |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
|
Phone |
+91 22 65113333 / 5555 / 9999 / 27611360 |
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Fax |
+91 22 2781 1318 :::AOH :0091 9821214367 |
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Email |
mail@rxmarine.com |
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Chemical Name
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CAS Number
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EC Number
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Index number
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Methyl Acrylate
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96-33-3
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202-500-6
|
607-034-00-0
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Hazard description:
Information concerning particular hazards for human and environment:
R 11 Highly flammable.
R 20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
R 36/37/38 Irritating to eyes, respiratory system and skin.
R 43 May cause sensitisation by skin contact.
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General information |
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48 hours after the accident. |
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After inhalation
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Supply fresh air and to be sure call for a doctor. In case of unconsciousness place patient stably in side position for transportation.
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After skin contact
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Immediately wash with water and soap and rinse thoroughly.
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After eye contact
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Rinse opened eye for several minutes under running water.If symptoms persist, consult a doctor.
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After swallowing
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Call for a doctor immediately.
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Suitable extinguishing agents:
CO2, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents: Water with full jet
Protective equipment: Mouth respiratory protective device.
Person-related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: Do not allow to enter sewers/ surface or ground water.
Measures for cleaning/collecting:
Absorb with liquid-binding material (sand, diatomite, acid binders, universal binders, sawdust).
Dispose contaminated material as waste according to item 13. Ensure adequate ventilation
Handling:
Information for safe handling: Ensure good ventilation/exhaustion at the workplace.
Information about fire - and explosion protection:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles: Store in a cool location.
Information about storage in one common storage facility: Not required.
Further information about storage conditions: Keep container tightly sealed. Store in cool, dry conditions in well sealed receptacles
Additional information about design of technical facilities: No further data; see item 7.
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Ingredients with limit values that require monitoring at the workplace: |
|
96-33-3 methyl acrylate |
|
PEL (USA)
REL (USA)
TLV (USA)
|
35 mg/m³, 10 ppm
Skin
35 mg/m³, 10 ppm
Skin
7 mg/m³, 2 ppm
Skin; SEN |
Additional information: The lists valid during the making were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing Wash hands before breaks and at the end of work. Avoid contact with the eyes and skin.
Respiratory protection: In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure use self-contained respiratory protective device.
Protection of hands:
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation. Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture. Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material of gloves:
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and
varies from manufacturer to manufacturer.
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection: Tightly sealed goggles
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General Information
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Form
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Fluid
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Colour
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Colourless
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Odour
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Pungent
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Change in condition
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Melting point/Melting range
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-76.5°C
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Boiling point/Boiling range
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80.5°C
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Flash point
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-3°C
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Ignition temperature |
415°C |
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Danger of explosion
|
Product is not explosive. However, formation of explosive air/vapour mixtures are possible.
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Explosion limits: |
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Lower |
2.4 Vol % |
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Upper |
18.6 Vol % |
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Vapour pressure at 20°C |
89 hPa |
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Density at 20°C |
0.9535 g/cm³ |
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Solubility in / Miscibility with water at 20°C |
60 g/l |
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Viscosity: |
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Dynamic at 22°C |
32 mPas |
Thermal decomposition / conditions to be avoided: No decomposition if used according to specifications.
Dangerous reactions No dangerous reactions known.
Dangerous decomposition products: No dangerous decomposition products known.
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Acute toxicity: |
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LD/LC50 values relevant for classification: |
|
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Oral
Dermal
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LD50
LD50
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277 mg/kg (rat)
1243 mg/kg (rabbit)
|
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Primary irritant effect: |
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on the skin |
Irritant to skin and mucous membranes. |
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on the eye |
Irritating effect. |
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Sensitization |
Sensitization possible through skin contact. |
General notes: Water hazard class 2 (German Regulation) (Assessment by list): hazardous for water Do not allow product to reach ground
water, water course or sewage system. Danger to drinking water if even small quantities leak into the ground.
Product:
• Recommendation : Must not be disposed together with household garbage. Do not allow product to reach sewage system.
• Uncleaned packaging: Recommendation: Disposal must be made according to official regulations.
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Land transport ADR/RID (cross-border) |
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ADR/RID class |
3 Flammable Liquids. |
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Danger code (Kemler) |
339 |
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UN-Number |
1919 |
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Packaging group |
II |
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Hazard label |
3 |
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Description of goods |
1919 METHYL ACRYLATE, STABILIZED |
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Maritime transport IMDG |
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IMDG Class |
3 |
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UN Number |
1919 |
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Label |
3 |
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Packaging group |
II |
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EMS Number |
F-E,S-D |
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Marine pollutant |
No |
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Proper shipping name |
METHYL ACRYLATE, STABILIZED |
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Air transport ICAO-TI and IATA-DGR |
|
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ICAO/IATA Class |
3 |
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UN/ID Number |
1919 |
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Label |
3 |
|
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Packaging group |
II |
|
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Proper shipping name |
METHYL ACRYLATE, STABILIZED |
• Labelling according to EU guidelines:
The product has been classified and marked in accordance with EU Directives / Ordinance on Hazardous Materials.
• Risk phrases:
11 Highly flammable.
20/21/22 Harmful by inhalation, in contact with skin and if swallowed.
36/37/38 Irritating to eyes, respiratory system and skin.
43 May cause sensitisation by skin contact.
• Safety phrases:
2 Keep out of the reach of children.
9 Keep container in a well-ventilated place.
25 Avoid contact with eyes.
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
This information is based on our present knowledge.However, this shall not constitute a guarantee for anys pecific product features and shall not
establish a legally valid contractual relationship.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.