
|
Product Name |
Methanol For Deicing
|
|
Part Number |
RXSOL-81-8200-210 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Gandhidham, Muscat, Fujairah, Chennai, Kolkata, Visakhapatnam

|
Component |
EC No |
CAS-No |
Weight % |
Classification |
|
2.METHYLPROPAN-2 OL |
200-889-7 |
75.65.0 |
1% |
F,R11 Xn, R 20 |
|
METHANOL |
200-659-7 |
87.56.1 |
99% |
F,R 11TR23/24/25,R39/23/24/25 |
|
|
|
|
|
|

|
Signal Word |
: |
Flammable |
|
Hazard Statements |
: |
Highly flammable Toxic by Inhalation, in contact with skin and it swallowed. |
|
Label Elements |
: |
Tixic, danger of very derious irreversible effects through inhalation, in contact with skin and it swallowed. |
|
Environmental hazards |
: |
Environmental effects Dangerous for the environment Very toxic to aquatic organisms; may cause long term adverse effects in the aquatic environment. T,R 23,/24/25, R 39/23/24/25 F,R 11 |

|
Inhalation |
Remove victim immediately from source of expourse. Provide Rest, warmth and fresh air.Get medical attention. If Respiratory problem artificial Respration / Oxygen. |
|
Ingestion |
DOES NOT INDUCE VOMITING, Rinse mouth thoroughly, Drink plenty of water, Get medical attention immediately.NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUID |
|
Skin Contact |
Wash the skin immediately with soap and water. Get medical attention promptly, if symtoms occur after washing. |
|
Eye Contact |
Properly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Get medical attention promptly, if symptoms occur after washing. |

|
Extinguishing Media |
Fiire can be extinguished using : Water spray, feg or mist.Alcohol resistant foam. Dry Chemicals,sand, dolomite etc. |
|
Special Fire Fighting Procedure |
Use supplied air respirator if product is involved in a fire. Cool containers exposed to flames with water until well until well after the fire is out. |
|
Specific Hazard |
Vapours / gases/ fumes of Carbon Dioxide ( CO 2). Carbon Monoxide ( CO) |

|
Personal Precaution |
Wear suitable protective clothing, gloves and safety goggles. |
|
Enviroment Precaution |
Dike to prevent enter any sewer or waterway. |
|
Spill Clean Method |
Extingush all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate,Absorb in vermiculite, dry sand or earth and place into containers. |

|
Usage Precautions |
Keep away from heat, sparks and open flame. Ventilate well. avoid breathing vapours. Use approved respirator if ait contamination is above accepted level. Avoid spilling,skin and eye contact. |
|
Storage Precaution |
The drums should be stored with their seal intact, in conditions that avoid extremes of temperatures. Bulk deliveries should be stored in carbon steel tanks. Under these conditions the shelf life of the product shouls be approximately two years. |
|
Storage Class |
Flammable liquid srorage. Toxic storage. |

|
Name |
Std |
LT-ppm |
LT mg/m3 |
ST ppm |
ST mg/m3 |
|
2. METHYLPROPAN 2 OL |
WEL |
100 ppm |
306 mg/m3 |
150 ppm |
462 mg/m3 |
|
MRTHANOL |
WEL |
200 ppm(Sk) |
260/mg/m3 (SK) |
250 ppm (Sk) |
333 mg/M3 (SK) |
INGREDIENT COMMENTS
WEL - Worl place Exposure Limits
Protective Equipment

Gloves Suit
|
Process Condition |
Use Engineering control to reduce Air contamination to permissible exposure level. |
|
Engineering Measures |
Explosion - proof general and local exahust ventialtion. |
|
Respiratory Equipment |
Use chemical cartridge protection with appropriate cartridge.Chemical respirator with organic vapour cartridge. |
|
Hand Protection |
Use protective gloves made of - Neoprane , Nitrile, polythene or pvc. |
|
Eye Protection |
Wear approved chemical safety gogle wher eye exposure is reasonably probable |
|
Other Protection |
Wear appropriate clothing to prevent repeated or prolonged skin contact. |
|
Hygiene Measures |
Wash at end of the each work shift at before eating, smoking and using the toilet. Wash promptly with soap and water if skin become contaminated. Promptly remove any clothing that become contaminated. |

|
Physical State |
: |
Liquid |
|
Appearance |
: |
Clear Liquid |
|
Odour |
|
Odour of Alcohol. |
|
Solubility |
: |
Soluble in Water |
|
Melting Point |
: |
- 40 |
|
Relative Density |
: |
0.790 - 0.800 @ 16°C |
|
Viscosity |
: |
10 cSt |
|
Flash Point |
: |
Min 11 PM Closes cup |

|
Stability |
No particular stability concern |
|
Condition to Avoid |
Avoid contact with strong oxidisers |
|
Hazardous Polymerisation |
Will not polymerise |
|
Material to Avoid |
Strong oxdising substances |
|
Hazardous composition |
Vapours/ gases /fumes of Carbon Dioxide (CO2) Carbon monoxide (CO). |

|
Inhalation |
Toxic by inhalation. Toxic danger of very serious irreversible effects through inhatation. Vapor have a nrcoti effect and may cause head ache, fatigue, dizziness and nausea. |
|
Skin Contact |
Toxic if sallowed. Toxic danger of very serious irreversible effects if swallowed. May cause nausea, head ache,dizziness and intoxication. |
|
Eye Contact |
Toxic in contact with skin. Toxic danger of very serious irreversible effects in contact with skin. May be absorbed through the skin. |

|
Bio Accumulation |
Being water souable would not be expected to bioaccumulate. |
|
Acute Fish Toxicity |
Typical acuatic toxicity data for this type of product are 10-100 mg/l to marine fish. |

|
Disposal Method |
Absorb in vermiculite or dry sand dispose in licensed hazardous waste. Dispose of waste and residues in accordance with local authority requirements. |
|
Wast Class |
The definitive European waste code for this product will depend upon the final use that is made of this material. If the material as originally delivered is to be disposed of please contact Baker Petrolite HSE Q & RA dept for assistance assigning the correct EU waste code. |

UK ROAD CLASS 3
PROPER SHIPPING NAME FLAMMABLE LIQUID, TOXIC N O S ( CONTAINS METHANOL)
UN NO ROAD 1993
UK ROAD PACK GR 8
ADR CLASS NO 3
ADR CLASS Class 3 Flamable
ADR PACK GROUP 8
ADR LEBEL NO 3 & 6.1
HAZ CHEM CODE 3 WE
RID CLASS NO 3
RID PACK GROUP II
UN NO SEA 1992
IMDG CLASS 3
IMDG PACK GR 8
MARINE POLLUTANT NO
UN NO AIR 1992
AIR CLASS 6.1
AIR PACK GR 8

LABELLING
CONTAINS METHNOL
RISK PHRASES R11 Highly flammable
R 23/24/25 Toxic by inhalation in contact with skin and if sallowed.
R 39/23/24/25 Toxic danger of very serious irreversible effects through inhalation, in contact with skin and if
swallowed.
S 16
S38 In case of in sufficient ventilation, wear suitable ventilation.
S 36/37/39 Wear suitable protrctive clothing, gloves and eye/face protection.
UK REGULATORY REFERENCES
CHEMICALS ( Hazard information & Packaging ) Regulations. The control of substances Hazardos to Health Regulatuons.
EU DIRECTIVES
Dangerous substance Directive 67/548/EEC .Dangerous Preparations. Directive 1999/45/EC.

RISK PHRASES IN FULL
R11 Highly flammable
R 20 Harmful by inhalation
R 23/24/26 Toxic by inhalation in contact with skin and if swallowed.
R 39/23/24/25 Toxic danger of very serious irreversible effects through inhalation in contact with skin and if swallowed.
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if RX Marine International has been advised of the possibility of such damages.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.