Name: Dichloro Benzene (O-)
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-19-1298-050

Dichloro Benzene (O-)

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Part No: RXSOL-19-1298-050

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Safety data (MSDS)

Product Name	Dichloro Benzene (O-)
Part Number	RXSOL-19-1298-050

Company Details:

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.comA

Chemical Name	CAS	EC number	Weight	Formula
Dichlorobenzene	95-50-1	202-425-9	= 100 %	C₆H₄Cl₂

Signal Word	Warning
Hazard Statements	H302 + H332 Harmful if swallowed or if inhaled. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements	P273 Avoid release to the environment. P280 Wear protective gloves/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 IF ON SKIN: Wash with plenty of water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Classification of the substance or mixture	Not a hazardous substance or mixture according to Regulation (EC) No 1272/2008.
Supplemental Hazard Statements	None
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.

General advice	Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air.
Eye Contact	After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses.
Swallowed	After swallowing: immediately make victim drink water (two glasses at most). Consult a physician..
Skin Contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician.
Inhalation	Remove patient to fresh air, keep warm and at rest and get medical assistance in necessary.
Ingestion	Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately.
Most important symptoms and effects, both acute and delaye	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

Flammability	Use water spray, alcohol-resistant foam, dry chemical or carbon dioxide.
Flash Point	Dry powder Dry sand
Suitable extinguishing media	Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Carbon oxides Hydrogen chloride gas Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire.
Further information	Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system.
Hazardous combustion products	Fire may cause the evolution of Sulphur oxides, nitrogen oxides.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Protective Equipment	Use personal protective equipment.
Specific Hazards Arising from the Chemical	Oxides of phosphorus Sodium oxides Not combustible. Fire may cause evolution of: Oxides of phosphorus Ambient fire may liberate hazardous vapours.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Spillage	Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal.
Enviromental Precaution	Do not let product enter drains.
Methods and materials for containment and cleaning	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area.

Advice on protection against fire and explosion	Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge.
Incompatible materials	Keep away from alkalis, strong oxidizing agents and metals. Provide containment walls of adequate capacity to hold any accidental spills.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Precautions for safe handling	Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols.
Storage conditions	Tightly closed. Keep in a well-ventilated place. Keep locked up or in an area accessible only to qualified or authorized persons. Light sensitive.
Storage class	Storage class (TRGS 510): 6.1C: Combustible, acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated
Advice on general occupational hygiene	Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance.
Requirements for storage	Keep in cool and store under shade.

Derived No Effect Level (DNEL)

Application Area	Routes of exposure	Health effect	Value
Worker DNEL, longterm	inhalation	Systemic effects	20 mg/m3
Worker DNEL, acute	inhalation	Systemic effects	100 mg/m3
Worker DNEL, longterm	inhalation	Local effects	10 mg/m3
Worker DNEL, acute	inhalation	Local effects	10 mg/m3

Predicted No Effect Concentration (PNEC)

Compartment	Value
Fresh water	0,0037 mg/l
Sea water	0,00037 mg/l
Sewage treatment plant	4,7 mg/l
Fresh water sediment	0,177 mg/kg

Exposure controls	Appropriate engineering controls Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Control parameters	Ingredients with workplace control parameters Contains no substances with occupational exposure limit values.
Engineering Control	Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday.
Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses
Body Protection	Protective clothing
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Viton® Minimum layer thickness: 0,7 mm Break through time: 480 min Material tested:Vitoject® (KCL 890 / Aldrich Z677698, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 30 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M)
Respiratory protection	Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Other Protection Measure	Handle in accordance with good industrial hygiene and safety practice.
Control of environmental exposure	Do not let product enter drains.

Physical state	Liquid, clear
Colour	Colorless, to, light yellow
Odour	Characteristic
Odor Threshold	No data available
pH	No data available
Melting Point	18 - -17 °C - lit.
Boiling Point	178 - 180 °C - lit.
Flash Point	66,0 °C - closed cup
Evaporation Rate	Not Applicable
Flammability (solid, gas)	No data available
Explosive limits	No Data Available
Upper/lower flammability or explosive limits	9,2 %(V) / 2,2 %(V)
Autoignition temperature	648,0 °C
Decomposition temperature	No data available
Vapour pressure	2,1 hPa at 35,0 °C
Density	1,306 g/cm3 at 25 °C - lit.
Relative Density	No data available
Relative vapor density	No data available
Freezing point	No data available
Viscosity	ca.1,324 mPa.s at 25 °C
Partition coefficient	log Pow: 3,43 at 25 °C
Explosive properties	No data available
Solubility	ca.0,1558 g/l at 25 °C
Ignition temperature	No information available.
Particle characteristics	No data available

Reactivity	Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical.
Stability	The product is chemically stable under standard ambient conditions (room temperature) .
Possibility of hazardous reactions	Violent reactions possible with: Strong oxidizing agents Alkali metals Alkaline earth metals Aluminum Light metals
Conditions to avoid	Strong heating.
Incompatible materials	Aluminum, rubber, various plastics
Hazardous decomposition products	In the event of fire: see section 5

Acute toxicity	LD50 Oral - Rat - male and female - 2.000 mg/kg (OECD Test Guideline 401) Remarks: (Regulation (EC) No 1272/2008, Annex VI) Acute toxicity estimate Inhalation - 4 h - 11,1 mg/l - vapor (Expert judgment) Remarks: (Regulation (EC) No 1272/2008, Annex VI) LD50 Dermal - Rabbit - > 10.000 mg/kg Remarks: (RTECS)
Skin corrosion/irritation	Skin - Rabbit Result: Skin irritation - 24 h (OECD Test Guideline 404)
Serious eye damage/eye irritation	Remarks: Causes serious eye irritation. Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2)
Respiratory or skin sensitization	Local lymph node assay (LLNA) - Mouse Result: positive (OECD Test Guideline 429)
Toxic Effects on Human	May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer).
Carcinogenicity	No data available
Germ cell mutagenicity	Test Type: Ames test Test system: Escherichia coli/Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Test Type: Mutagenicity (mammal cell test): chromosome aberration. Test system: lymphocyte Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 473 Result: negative Test Type: In vitro mammalian cell gene mutation test Test system: Chinese hamster ovary cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: In vivo micronucleus test Species: Mouse Cell type: Bone marrow Application Route: Intraperitoneal injection Method: OECD Test Guideline 474 Result: negative
Reproductive toxicity	No data available
Specific target organ toxicity - single exposure	No data available
Special Remarks on other Toxi Effects on Humans	Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Repeated dose toxicity - Rat - male and female - Oral - 24 h - NOAEL (No observed adverse effect level) - 60 mg/kg - LOAEL (Lowest observed adverse effect level) - 125 mg/kg Remarks: (ECHA) RTECS: CZ4500000 To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigated.

Bioaccumulative potential	Bioaccumulation Cyprinus carpio (Carp) - 56 d - 0,01 mg/l(1,2-Dichlorobenzene)
Persistence and degradability	Biodegradability aerobic - Exposure time 28 d Result: 0 % - Not readily biodegradable. (OECD Test Guideline 301C)
Toxicity to fish	Flow-through test LC50 - Oncorhynchus mykiss (rainbow trout) - 1,58 mg/l - 96 h Remarks: (ECHA)
Toxicity to daphnia and other aquatic invertebrates	Static test EC50 - Ceriodaphnia dubia (water flea) - 0,66 mg/l - 48 h (US-EPA)
Toxicity to algae	Growth rate EC50 - Pseudokirchneriella subcapitata (green algae) - 2,2 mg/l - 96 h (US-EPA)
Toxicity to bacteria	Static test EC50 - activated sludge - 563 mg/l - 3 h (OECD Test Guideline 209) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: sodium hypochlorite solution
Mobility in soil	No Information available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.
Other adverse effects	No data available

Disposal methods	The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

UN number	ADR/RID: 1591 IMDG: 1591 IATA: 1591
UN proper shipping name	ADR/RID:DICHLOROBENZENE IMDG: DICHLOROBENZENE IATA:DICHLOROBENZENE
Transport hazard class(es)	ADR/RID: 6.1 IMDG: 6.1 IATA: 6.1
Packaging group	ADR/RID: III IMDG: III IATA: III
Environmental hazards	ADR/RID: YES IMDG: YES IATA: NO
Further information	No data available

Inventory status	Components are on the following inventories: Polymaleic acid: - US TSCA, Canadian DSL, EU EINECS, Australian AICS, Korean, Philippine PICCS and Chinese Xi irritant R 36/38 Irritant to eyes & skin R 41 Risk of serious damage to eyes S24/25 Avoid contact with skin and eyes S26/28 In case of contact eyes & skin, rinse with plenty water and seek medical advice Section 312/313: Not listed. Not listed under California proposition 65.
Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
National legislation	Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ENVIRONMENTAL HAZARDS
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.

PRODUCT NAME	:	DICHLOROBENZENE (O-)
CAS number	:	95-50-1
UN number	:	1591
Formula	:	C6H4CI2
Odour	:	PLEASANT
Solubility in water	:	INSOLUBLE
Density	:	1.305 at 20 ^oC
Boiling point	:	172 ^oC
Melting point	:	-17 ^oC
Viscosity	:
Flashpoint	:	66^oC
Explosive limits	:	2.2 – 12 Vol%
Vapour pressure	:	1.3 mbar at 20 ^oC
Skin absorption/irritation	:	YES
TLV Country NL	:	25 C ppm 150 C mg/m3
Pollution category 1994	:	B

Dichloro Benzene (O-)

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