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Part No: RXSOL-19-1284-200
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Safety data (MSDS)
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Product Name |
Cyclo Hexanol |
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Part Number |
RXSOL-19-1284-200 |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA
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Phone |
+91 22 20871200 - 1400 |
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Fax |
+91 22 27612100 :::AOH :0091 9821214367 |
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Email |
mail@rxmarine.com |
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Website |
www.rxmraine.com |
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Chemical Name |
CAS |
EC number |
Weight |
Formula |
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Cyclo Hexanol |
108-93-0 |
203-630-6 |
= 100 % |
C6H12O |
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Signal Word |
Warning |
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Classification of the substance or mixture |
Acute toxicity, Oral (Category 4), H302 Acute toxicity, Inhalation (Category 4), H332 Acute toxicity, Dermal (Category 4), H312 Skin irritation (Category 2), H315 Eye irritation (Category 2), H319 Specific target organ toxicity - single exposure (Category 3), Respiratory system, H335 Long-term (chronic) aquatic hazard (Category 3), H412 |
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Hazard Statements |
H302 + H312 + H332 Harmful if swallowed, in contact with skin or if inhaled.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H335 May cause respiratory irritation.
H412 Harmful to aquatic life with long lasting effects.
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P280 Wear protective gloves.P305 + P351 + P338 |
Wear eye protection/ face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Precautionary statements |
P273 Avoid release to the environment. P280 Wear protective gloves/ protective clothing/ eye protection/ face protection. P301 + P312 IF SWALLOWED: Call a POISON CENTER/ doctor if you feel unwell. P302 + P352 + P312 IF ON SKIN: Wash with plenty of water.Call a POISON CENTER/ doctor if you feel unwell. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. |
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Response |
None |
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Disposal |
P501 Dispose of contents/container to an appropriate treatment and disposal facility in accordance with applicable laws and regulations, and product characteristics at time of disposal. |
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Prevention |
P273 Avoid release to the environment. |
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Supplemental Hazard Statements |
None |
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Other hazards |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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General advice |
Show this material safety data sheet to the doctor in attendance. |
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If inhaled |
After inhalation: fresh air |
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Eye Contact |
After eye contact: rinse out with plenty of water. Call in ophthalmologist. Remove contact lenses. |
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Swallowed |
After swallowing: immediately make victim drink water (two glasses at most). Consult a physician. |
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Skin Contact |
In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Consult a physician. |
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Inhalation |
Move to fresh air. If breathing is difficult, give oxygen. Get medical attention immediately if symptoms occur. |
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Ingestion |
Rinse mouth with water. Do not induce vomiting. Never give anything by mouth to an unconscious person. Call a doctor or Poison Control Center immediately. |
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Notes to Physician |
Treat symptomatically |
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Most important symptoms and effects, both acute and delaye |
The most important known symptoms and effects are described in the labelling |
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Indication of any immediate medical attention and special treatment needed |
No data available |
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Flammability |
May be combustible at high temperature. |
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Flash Point |
Higher than 93.3°C (200°F). |
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Suitable extinguishing media |
Carbon dioxide (CO2) Foam Dry powder |
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Unsuitable extinguishing media |
For this substance/mixture no limitations of extinguishing agents are given. |
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Special hazards arising from the substance or mixture |
Carbon oxides Combustible. Vapors are heavier than air and may spread along floors. Forms explosive mixtures with air on intense heating. Development of hazardous combustion gases or vapours possible in the event of fire. |
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Further information |
Remove container from danger zone and cool with water. Prevent fire extinguishing water from contaminating surface water or the ground water system. |
Hazardous combustion
products |
Fire may cause the evolution of Sulphur oxides, nitrogen oxides. |
|
Advice for firefighters |
Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing. |
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Protective Equipment |
Use personal protective equipment. |
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Specific Hazards Arising from the Chemical |
Has a fire-promoting effect due to the release of oxygen.
Ambient fire may liberate hazardous vapours. |
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Personal precautions, protective equipment and emergency procedures |
Advice for non-emergency personnel: Do not breathe vapors, aerosols. Avoid substance contact. Ensure adequate ventilation. Keep away from heat and sources of ignition. Evacuate the danger area, observe emergency procedures, consult an expert. |
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Spillage |
Oxidizing material. Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas dike if needed. Eliminate all ignition sources. Call for assistance on disposal. |
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Personal Protection |
Advice for non-emergency personnel: Avoid inhalation of dusts. Evacuate the danger area, observe emergency procedures, consult an expert. Advice for emergency responders: Protective equipment see section 8. |
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Enviromental Precaution |
Do not let product enter drains. |
Methods and materials for
containment and cleaning |
Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up with liquid-absorbent material (e.g. Chemizorb® ). Dispose of properly. Clean up affected area. |
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Reference to other sections |
For disposal see section 13. |
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Advice on safe handling |
Work under hood. Do not inhale substance/mixture. Avoid generation of vapours/aerosols. |
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Advice on protection against fire and explosion |
Keep away from open flames, hot surfaces and sources of ignition.Take precautionary measures against static discharge. |
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Hygiene measures |
Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. |
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Precautions for safe handling |
Handling in a well ventilated place. Wear suitable protective clothing. Avoid contact with skin and eyes. Avoid formation of dust and aerosols. Use non-sparking tools. Prevent fire caused by electrostatic discharge steam. |
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Conditions for safe storage, including any incompatibilities |
Store the container tightly closed in a dry, cool and well-ventilated place. Store apart from foodstuff containers or incompatible materials. |
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Storage conditions |
Tightly closed. hygroscopic |
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Storage class |
Storage class (TRGS 510): 10: Combustible liquids |
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Specific end use(s) |
Apart from the uses mentioned in section 1.2 no other specific uses are stipulated |
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Handling |
Keep away from heat. Keep away from sources of ignition. Keep away from combustible material.. Empty containers pose a fire risk, evaporate the residue under a fume hood. Ground all equipment containing material. Do not ingest. Do not breathe dust. Wear suitable protective clothing. In case of insufficient ventilation, wear suitable respiratory equipment. If ingested, seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes. Keep away from incompatibles such as reducing agents, combustible materials, organic materials, metals |
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Advice on general occupational hygiene |
Advice on safe handling Observe label precautions. Change contaminated clothing. Wash hands after working with substance. |
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Occupational Exposure limit values |
No data available |
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Biological limit values |
No data available |
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Exposure controls |
Ensure adequate ventilation. Handle in accordance with good industrial hygiene and safety practice. Set up emergency exits and the riskelimination area |
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Engineering Control |
Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. |
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Eye/face protection |
Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Safety glasses |
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Body Protection |
protective clothing |
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Skin protection |
This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Nitrile rubber Minimum layer thickness: 0,4 mm Break through time: 480 min Material tested:Camatril® (KCL 730 / Aldrich Z677442, Size M) This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN374 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 240 min Material tested:KCL 720 Camapren® |
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Respiratory protection |
Recommended Filter type: Filter A (acc. to DIN 3181) for vapours of organic compounds The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented. |
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Other Protection Measure |
Handle in accordance with good industrial hygiene and safety practice. |
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Control of environmental exposure |
Do not let product enter drains. |
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Thermal hazards |
No data available |
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Physical state |
Liquid |
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Colour |
No data available |
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Odour |
No data available |
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Odor Threshold |
Not Applicable |
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pH |
6,5 at 40 g/l at 20 °C |
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Melting Point |
25,4 °C |
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Boiling Point |
160 - 161 °C |
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Flash Point |
64 °C - closed cup - DIN 51794 |
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Evaporation Rate |
Not Applicable |
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Flammability (solid, gas) |
No data available |
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Explosive limits |
No Data Available |
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Upper/lower flammability or explosive limits |
Upper explosion limit: 12,25 %(V) Lower explosion limit: 1,25 %(V) |
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Autoignition temperature |
285 °C at 1.013,25 hPa - DIN 51794 |
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Dynamic Viscosity |
53,3 mPa.s at 27 °C |
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Decomposition temperature |
No data available |
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Vapour pressure |
1,1 hPa at 25 °C - OECD Test Guideline 104 |
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Density |
0,948 g/cm3 at 25 °C - lit |
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Vapour Density |
No Data Available |
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Specific Gravity |
No data available |
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Partition coefficient |
1,25 at 25 °C |
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Explosive properties |
None |
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Solubility |
37,6 g/l at 25,1 °C - soluble |
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Ignition temperature |
No information available. |
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Particle characteristics |
No data available |
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Surface tension |
66,87 mN/m at 1,4g/l at 25 °C |
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Relative vapor density |
4,01 |
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Reactivity |
Forms explosive mixtures with air on intense heating. A range from approx. 15 Kelvin below the flash point is to be rated as critical. |
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Stability |
The product is chemically stable under standard ambient conditions (room temperature). |
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Possibility of hazardous reactions |
No data available |
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Conditions to avoid |
Strong heating. |
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Incompatible materials |
No data available |
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Hazardous Polymerization |
In the event of fire: see section 5 |
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Acute toxicity |
LD50 Oral - Rat - 1.400 mg/kg Remarks: Behavioral:Somnolence (general depressed activity). Lungs, Thorax, or Respiration:Other changes. Nutritional and Gross Metabolic:Weight loss or decreased weight gain. (RTECS) Acute toxicity estimate Oral - 1.400 mg/kg (ATE value derived from LD50/LC50 value) Acute toxicity estimate Inhalation - 4 h - 11 mg/l - vapor (Expert judgment) Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) Acute toxicity estimate Dermal - 1.500 mg/kg (Expert judgment) Remarks: (ECHA) |
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Skincorrosion/irritation |
Skin - Rabbit Result: Skin irritation - 24 h Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
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Serious eye damage/eye irritation |
Eyes - Rabbit Result: Causes serious eye irritation. (OECD Test Guideline 405) |
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Respiratory or skin sensitization |
Maximization Test - Guinea pig Result: negative (OECD Test Guideline 406) |
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Serious eye damage/eye irritation |
No data available |
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Toxicity to Animal |
WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE Acute oral toxicity (LD50): 689 mg/kg [Rat]. |
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Toxic Effects on Human |
May cause damage to the following organs: upper respiratory tract. Other Toxic Effects on Humans: Hazardous in case of skin contact (irritant, sensitizer), of ingestion, of inhalation (lung irritant, lung sensitizer). |
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Germ cell mutagenicity |
In vitro mammalian cell gene mutation test Test system: mouse lymphoma cells Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 476 Result: negative Test Type: Ames test Test system: Salmonella typhimurium Metabolic activation: with and without metabolic activation Method: OECD Test Guideline 471 Result: negative Remarks: (IUCLID) Species: Mouse Cell type: Bone marrow Application Route: Oral Method: OECD Test Guideline 474 |
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Carcinogenicity |
No data available |
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Reproductive toxicity |
No data available |
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Specific target organ toxicity - single exposure |
May cause respiratory irritation. Remarks: Classified according to Regulation (EU) 1272/2008, Annex VI (Table 3.1/3.2) |
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Special Remarks on other Toxi Effects on Humans |
Acute Potential Health Effects: Skin: Causes skin irritation. May cause skin sensitization, an allergic reation, which becomes evident upon re-exposure to this material. Eyes: Causes eye irritation. Ingestion: Causes gastrointestinal (digestive) tract irritation with nausea, vomiting, and diarrhea. May be harmful if swallowed. Inhalation: Causes respiratory tract irritation. May cause chemical pneumonitis and pulmonary edema, inflammation, edema of bronchi and larynx. Chronic Potential Health Effects: Repeated or prolonged skin exposure may cause allergic reactions in sensitive individuals. Repeated or prolonged exposure by inhalation may affect respiration and metabolism. |
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Aspiration hazard |
No data available |
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Additional Information |
Endocrine disrupting properties |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.Repeated dose toxicity - Rat - male and female - NOAEL (No observed adverse effect level) - 6 mg/kg |
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Persistence and degradability |
Biodegradability aerobic - Exposure time 28 d Result: 94 - 99 % - Readily biodegradable. (OECD Test Guideline 301C) |
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Toxicity |
Toxicity to fish: no data available Toxicity to daphnia and other aquatic invertebrates: no data available Toxicity to algae: no data available Toxicity to microorganisms: no data available |
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Bioaccumulative potential |
No data available |
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Toxicity to fish |
Flow-through test LC50 - Pimephales promelas (fathead minnow) - 704 mg/l - 96 h (US-EPA) |
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Toxicity to daphnia and other aquatic invertebrates |
Semi-static test NOEC - Daphnia magna (Water flea) - 0,953 mg/l - 21 d (OECD Test Guideline 211) semi-static test EC50 - Daphnia magna (Water flea) - 0,953 mg/l - 21 d (OECD Test Guideline 211) |
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Toxicity to algae |
Static test ErC50 - Desmodesmus subspicatus (green algae) - > 500 mg/l - 96 h (DIN 38412) ,static test NOEC - Desmodesmus subspicatus (green algae) - 0,03 mg/l - 96 h (DIN 38412) |
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Toxicity to bacteria |
Static test NOEC - activated sludge - 1.995 mg/l - 30 min (OECD Test Guideline 209) |
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COD and BOD 5 |
Not Available |
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Products Biodegradation |
The methods for determining the biological degradability are not applicable to inorganic substances. |
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Mobility in soil |
No Information available |
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Results of PBT and vPvB assessment |
This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. |
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Endocrine disrupting properties |
The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher |
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Other adverse effects |
No data available |
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Disposal methods |
The material can be disposed of by removal to a licensed chemical destruction plant or by controlled incineration with flue gas scrubbing. Do not contaminate water, foodstuffs, feed or seed by storage or disposal. Do not discharge to sewer systems. |
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Contaminated packaging |
Containers can be triply rinsed (or equivalent) and offered for recycling or reconditioning. Alternatively, the packaging can be punctured to make it unusable for other purposes and then be disposed of in a sanitary landfill. Controlled incineration with flue gas scrubbing is possible for combustible packaging materials. |
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Waste treatment Method |
See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions. |
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UN number |
ADR/RID: IMDG: IATA: |
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UN proper shipping name |
ADR/RID: Not dangerous goods
IMDG: Not dangerous goods
IATA: Not dangerous goods
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Transport hazard class(es) |
ADR/RID: IMDG: IATA: |
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Packaging group |
ADR/RID: IMDG: IATA: |
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Environmental hazards |
ADR/RID: No IMDG: No IATA: No |
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Special precautions for user |
Tunnel restriction code : (C/E) |
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Further information |
Not classified as dangerous in the meaning of transport regulations. |
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Transport in bulk according to IMOinstruments |
No data available |
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Safety, health and environmental regulations/legislation specific for the substance or mixture |
This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006 |
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Safety, health and environmental regulations specific for the product in question |
European Inventory of Existing Commercial Chemical Substances (EINECS) -Listed.EC Inventory Listed. United States Toxic Substances Control Act (TSCA) Inventory- Listed. China Catalog of Hazardous chemicals 2015 Not- Listed. New Zealand Inventory of Chemicals (NZIoC)Listed. PICCS -Listed. Vietnam National Chemical Inventory -Listed. IECSC Listed. Korea Existing Chemicals List (KECL) -Listed. |
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National legislation |
Seveso III: Directive 2012/18/EU of the European Parliament and of the Council on the control of major-accident hazards involving dangerous substances. : ACUTE TOXIC : ENVIRONMENTAL HAZARDS |
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DSCL (EEC) |
R8- Contact with combustible material may cause fire. R20/22- Harmful by inhalation and if swallowed. R36/37/38- Irritating to eyes, respiratory system and skin. R42/43- May cause sensitization by inhalation and skin contact. S22- Do not breathe dust. S24- Avoid contact with skin. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. S37- Wear suitable gloves. |
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Other regulations |
Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable.Take note of Dir 94/33/EC on the protection of young people at work. |
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Chemical Safety Assessment |
For this product a chemical safety assessment was not carried out |
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Other Information |
The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.
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