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Part Number |
RXSOL-16-2063-210 |
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Product Name |
Biocide RX |
Company Details:
RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA
Stock Point : Mumbai, Kandla, Kolkata, Chennai, Visakhapatnam, Fujairah, Muscat, Nairobi
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Phone |
+91 22 65113333 / 5555 / 9999 / 27611360 |
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Fax |
+91 22 2781 1318 :::AOH :0091 9821214367 |
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Email |
mail@rxmarine.com |
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Product
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EINECS /
ELINCS NO
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SYMBOL
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R-PHRASES /
NOTAS
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% (w/w)
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Quaternary Ammonium compound
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Proprietary
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C, N
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R22, R34, R50
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10 - 30
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Pentane-1,5-dial ( Glutaraldehyde ) |
111-30-8 |
C, N |
R22, R34, R50 |
15-40 |
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Ethylene Glycol
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203-473-3
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Xn
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R22
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10 - 30
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Isopropanol
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200-661-7
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F, Xi
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R11, R36, R67
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10- 5
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Quaternary phosphorus compound
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Proprietary
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T, N |
R23, R22, R41,R43, R63, R50
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1 - 5
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Dipropylene Glycol Monomethyl Ether
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252-104-2
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OEL
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1 - 5 |
Refer to Section 16 for descriptions of relevant risk phrases and Notas
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HAZARD CLASSIFICATION :
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This product is classified as dangerous in accordance with the Preparations Directive 1999/45/EC. Flammable. Harmful if swallowed. Causes burns. May cause sensitization by skin contact
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HUMAN HEALTH HAZARDS - ACUTE :
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INHALATION :
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Irritating, in high concentrations, to the eyes, nose, throat and lungs.
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SKIN CONTACT :
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May cause severe irritation or tissue damage depending on the length of exposure and the type of first aid administered. Prolonged or frequently repeated skin contact may cause allergic reactions in some individuals
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EYE CONTACT
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Corrosive. Will cause eye burns and permanent tissue damage
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INGESTION :
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Not a likely route of exposure. Corrosive; causes chemical burns to the mouth, throat and stomach. Harmful if swallowed. Large quantities may cause kidney damage.
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HUMAN HEALTH HAZARDS - CHRONIC
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Contains ethylene glycol (EG). Repeated high dose exposure to EG by ingestion (animal studies) has caused kidney damage, brain damage, degeneration of the liver, changes in blood chemistry and circulating blood cells. Prolonged and/or repeated exposures may cause similar effects in humans. Ethylene glycol has been shown to cause developmental and reproductive effects at high dose levels in laboratory animals. The relationship of these results to humans has not been fully established. Prolonged exposure to ethylene glycol may cause central nervous system, kidney and liver effects.
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PHYSICAL AND CHEMICAL HAZARDS
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Flammable
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INHALATION :
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Get medical attention. Remove to fresh air, treat symptomatically
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SKIN CONTACT
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Get immediate medical attention. Immediately flush with plenty of water for at least 15 minutes. For a large splash, flood body under a shower. Remove contaminated clothing. Wash off affected area immediately with plenty of water. Contaminated clothing, shoes, and leather goods must be discarded or cleaned before re-use
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EYE CONTACT
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Get immediate medical attention. PROMPT ACTION IS ESSENTIAL IN CASE OF CONTACT. Immediately flush eye with water for at least 15 minutes while holding eyelids open
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INGESTION
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Get immediate medical attention. DO NOT INDUCE VOMITING. If conscious, washout mouth and give water to drink.
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NOTE TO PHYSICIAN
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Probable mucosal damage may contraindicate the use of gastric lavage. Based on the individual reactions of the patient, the physician's judgement should be used to control symptoms and clinical condition
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FLASH POINT :
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50 °C PMCC
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EXTINGUISHING MEDIA
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Foam, Carbon dioxide, Dry powder, Other extinguishing agent suitable for Class B fires, For large fires, use water spray or fog, thoroughly drenching the burning material. Water mist may be used to cool closed containers
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FIRE AND EXPLOSION HAZARD
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Combustible Liquid; may form combustible mixtures at or above the flash point. Empty product containers may contain product residue. Do not pressurize, cut, heat, weld, or expose containers to flame or other sources of ignition. May evolve oxides of carbon (COx) under fire conditions. May evolve oxides of nitrogen (NOx) under fire conditions. May evolve oxides of phosphorus (POx) under fire conditions
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SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING
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In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective suit
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PERSONAL PRECAUTIONS
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Restrict access to area as appropriate until clean-up operations are complete. Use personal protective equipment recommended in Section 8 (Exposure Controls/Personal Protection). Stop or reduce any leaks if it is safe to do so. Ventilate spill area if possible. Remove sources of ignition. Ensure clean-up is conducted by trained personnel only. Do not touch spilled material. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Notify appropriate government, occupational health and safety and environmental authorities
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METHODS FOR CLEANING UP
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SMALL SPILLS: Soak up spill with absorbent material. Place residues in a suitable, covered, properly labeled container. Wash affected area. LARGE SPILLS: Contain liquid using absorbent material, by digging trenches or by diking. Reclaim into recovery or salvage drums or tank truck for proper disposal. Clean contaminated surfaces with water or aqueous cleaning agents. Contact an approved waste hauler for disposal of contaminated recovered material. Dispose of material in compliance with regulations indicated in Section 13 (Disposal Considerations)
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ENVIRONMENTAL PRECAUTIONS
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Do not contaminate surface water
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HANDLING
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Do not get in eyes, on skin, on clothing. Do not take internally. Use with adequate ventilation. Do not breathe vapors/gases/dust. Keep the containers closed when not in use. Have emergency equipment (for fires, spills, leaks, etc.) readily available. Ensure all containers are labelled. Do not use, store, spill or pour near heat, sparks or open flame
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STORAGE CONDITIONS
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Store in suitable labelled containers. Store the containers tightly closed. Store away from heat and sources of ignition. Have appropriate fire extinguishers available in and near the storage area. Connections must be grounded to avoid electrical charges
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SUITABLE CONSTRUCTION MATERIAL
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HDPE (high density polyethylene), PTFE, FEP (encapsulated), Viton, Stainless Steel 304, Stainless Steel 316L, MDPE (medium density polyethylene), Surface-modified HDPE (high density polyethylene), Nitrile, EPDM, Perfluoroelastomer, Compatibility with Plastic Materials can vary; we therefore recommend that compatibility is tested prior to use
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UNSUITABLE CONSTRUCTION MATERIAL
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Carbon Steel C1018
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Substance(s) |
Method
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Analysis |
Absorbant
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Ethylene Glycol |
US NIOSH: 5523
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Gas chromatography |
XAD-7 / Glass fibre
filter OVS tube
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Isopropanol |
US NIOSH: 1400
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Gas chromatography |
Charcoal
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Dipropylene Glycol Monomethyl Ether |
US OSHA: 101
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Gas chromatography |
Charcoal
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BIOLOGICAL EXPOSURE INDICES
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Isopropanol
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A biological index of exposure to isopropyl alchohol (CAS 67-63-0) is the detection of acetone in the blood or urine post shift (50mg/l)
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ENGINEERING MEASURES
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General ventilation is recommended. The use of local exhaust ventilation is recommended to control emissions near the source. Laboratory samples should be handled in a fumehood. Provide mechanical ventilation of confined spaces.
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PERSONAL PROTECTION |
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GENERAL ADVICE
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The use and choice of personal protection equipment is related to the hazard of the product, the workplace and the way the product is handled. In general, we recommend as a minimum precaution that safety glasses with side-shields and workclothes protecting arms, legs and body be used. In addition any person visiting an area where this product is handled should at least wear safety glasses with side-shields. The applicable European standard can be found in EN 166.
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RESPIRATORY PROTECTION
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Where concentrations in air may exceed the limits given in this section, the use of a half face filter mask or air supplied breathing apparatus is recommended. A suitable filter material depends on the amount and type of chemicals being handled. Consider the use of filter type: A-B-E-K-P The applicable European standard can be found in EN 141, EN 143 and EN 371. In event of emergency or planned entry into unknown concentrations a positive pressure, full-facepiece SCBA should be used. If respiratory protection is required, institute a complete respiratory protection program including selection, fit testing, training, maintenance and inspection
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HAND PROTECTION
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When handling this product, the use of chemical gauntlets is recommended. The choice of work glove depends on work conditions and what chemicals are handled, but we have positive experience under light handling conditions using gloves made from PVC Gloves should be replaced immediately if signs of degradation are observed. Breakthrough time not determined as preparation, consult PPE manufacturers. The applicable European standard can be found in EN 374
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SKIN PROTECTION |
When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 467 and EN 345
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EYE PROTECTION
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When handling this product, the use of a chemical resistant suit and rubber boots is recommended. The applicable European standard can be found in EN 467 and EN 345
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EYE PROTECTION |
Wear a face shield with chemical splash goggles. The applicable European standard can be found in EN 166 |
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HYGIENE RECOMMENDATIONS |
Use good work and personal hygiene practices to avoid exposure. Keep an eye wash fountain available. Keep a safety shower available. If clothing is contaminated, remove clothing and thoroughly wash the affected area Launder contaminated clothing before reuse. Always wash thoroughly after handling chemicals. When handling this product never eat, drink or smoke
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PHYSICAL STATE |
Liquid |
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APPEARANCE |
Clear White |
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ODOR |
Slight |
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FLASH POINT |
50 °C PMCC |
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SPECIFIC GRAVITY |
1.016 (15 °C) |
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SOLUBILITY IN WATER |
Complete |
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pH (100 %) |
3.6 |
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VISCOSITY
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2.17 cst (40 °C) ASTM D-445 |
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MELTING POINT |
ASTM D-97 -13 °C
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Note: These physical properties are typical values for this product and are subject to change.
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STABILITY |
Stable under normal conditions |
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HAZARDOUS POLYMERIZATION |
Hazardous polymerization will not occur |
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CONDITIONS TO AVOID |
Heat and sources of ignition including static discharges |
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MATERIALS TO AVOID
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Contact with strong oxidizers (e.g. chlorine, peroxides, chromates, nitric acid, perchlorate, concentrated oxygen, permanganate) may generate heat, fires, explosions and/or toxic vapors., Contact with strong alkalies (e.g. ammonia and its solutions, carbonates, sodium hydroxide (caustic), potassium hydroxide, calcium hydroxide (lime), cyanide, sulfide, hypochlorites, chlorites) may generate heat, splattering or boiling and toxic vapors
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HAZARDOUS DECOMPOSITION PRODUCTS
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Under fire conditions
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Oxides of carbon, Oxides of nitrogen, Oxides of phosphorus
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No toxicity studies have been conducted on this product
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SENSITIZATION |
Repeated or prolonged contact may cause skin sensitization |
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CARCINOGENICITY |
None of the substances in this product are listed as carcinogens by the International Agency for Research on Cancer (IARC), the National Toxicology Program (NTP) or the American Conference of Governmental Industrial Hygienists (ACGIH) |
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TERATOGENICITY |
This material is not a teratogen, at low dose levels of 6 or 18 mg/kg/day for rabbits and 15 or 30 mg/kg/day for rats. At a high dose level of 60 mg/kg/day, both species showed fetal toxicity. |
For additional information on the hazard of the preparation, please consult section 3 and 12.
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ECOTOXICOLOGICAL EFFECTS |
No toxicity studies have been conducted on this product |
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MOBILITY |
The environmental fate of this product under the defined conditions of the models. If released into the environment this material is expected to distribute to the air, water and soil/sediment in the approximate respective percentages (Air-5%, Water- 30 - 50%, Soil/Sediment- 50 - 70%) The portion in water is expected to be soluble or dispersible |
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PERSISTENCY AND DEGRADATION
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The organic portion of this preparation is expected to be readily biodegradable
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BIOACCUMULATION POTENTIAL
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Component substances have a low potential to bioconcentrate
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Dispose of wastes in an approved incinerator or waste treatment/disposal site, in accordance with all applicable regulations. Do not dispose of wastes in local sewer or with normal garbage. This product is ashless and can be burned directly in appropriate equipment. This product is NOT suitable for disposal via municipal sewers, drains, natural streams or rivers.
Empty drums should be taken for recycling, recovery, or disposal through a suitably qualified or licensed contractor.
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EUROPE WASTE CODE |
16 03 05*- OFF SPECIFICATION BATCHES AND UNUSED PRODUCTS - Organic wastes containing dangerous substances. If this product is used in any further processes, the final user must redefine and assign the most appropriate European Waste Catalogue Code |
Typical Proper Shipping Names for this product are as follows.
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LAND TRANSPORT |
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Proper Shipping Name |
FLAMMABLE LIQUID, CORROSIVE, N.O.S. |
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Technical Name(s) |
Isopropanol, Quaternary Ammonium compound
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UN/ID No |
UN 2924 |
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Hazard Class - Primary |
3 |
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Hazard Class - Secondary
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8 |
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Packing Group
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III |
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ADR/RID H.I.n. :
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38 |
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CLASSIFICATION CODE
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FC |
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AIR TRANSPORT (ICAO/IATA)
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Proper Shipping Name
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FLAMMABLE LIQUID, CORROSIVE, N.O.S
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Technical Name(s) :
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Isopropanol, Quaternary Ammonium compound
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UN/ID No
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UN 2924
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Hazard Class - Primary
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3 |
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Hazard Class - Secondary
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8 |
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Packing Group
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III |
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IATA Cargo Packing Instructions
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310
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IATA Cargo Aircraft Limit
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60 L (Max net quantity per package)
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IATA Passenger Packing Instructions
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Y309 / 309
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IATA Passenger Aircraft Limit
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1 L / 5 L
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MARINE TRANSPORT (IMDG/IMO)
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Proper Shipping Name
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FLAMMABLE LIQUID, CORROSIVE, N.O.S.
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Technical Name(s) :
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Isopropanol, Quaternary Ammonium compound
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UN/ID No
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UN 2924
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Hazard Class - Primary
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3 |
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Hazard Class - Secondary
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8 |
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Packing Group
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III |
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OTHER APPLICABLE INFORMATION
CEFIC TREMCARD REFERENCE
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30GFC-III
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EMERGENCY ACTION CODE
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3W
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CLASSIFICATION AND LABELLING |
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GOVERNING DIRECTIVE(S): |
Dangerous Substances Directive 67/548/EEC and Dangerous Preparations Directive 1999/45/EC |
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HAZARD SYMBOLS |
CORROSIVE |
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Contains:..Quaternary Ammonium compound Quaternary phosphorus compound |
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RISK PHRASES |
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R10
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Flammable.
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R22
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Harmful if swallowed
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R34
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Causes burns
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R43
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May cause sensitization by skin contact
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SAFETY PHRASES
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S26
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In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
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S36/37/39
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Wear suitable protective clothing, gloves and eye/face protection.
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S45
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In case of accident or if you feel unwell, seek medical advice immediately (show the label where possible).
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INTERNATIONAL CHEMICAL CONTROL LAWS
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UNITED STATES
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The substances in this preparation are included on or exempted from the TSCA 8(b) Inventory (40 CFR 710)
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CANADA
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This product contains substance(s) which are found on the Non-Domestic Substances List (NDSL), or are not in compliance with other Canadian Acts
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EUROPE
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The substances in this preparation have been reviewed for compliance with the EINECS or ELINCS inventories
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JAPAN
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All substances in this product comply with the Law Regulating the Manufacture and Importation Of Chemical Substances and are listed on the Ministry of International Trade & industry List (MITI).
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LIST OF RELEVANT R-PHRASES AND NOTAS IN SECTION 2
R11 - Highly flammable.
R22 - Harmful if swallowed.
R23 - Toxic by inhalation.
R34 - Causes burns.
R36 - Irritating to eyes.
R41 - Risk of serious damage to eyes.
R43 - May cause sensitization by skin contact.
R50 - Very toxic to aquatic organisms.
R63 - Possible risk of harm to the unborn child.
R67 - Vapours may cause drowsiness and dizziness.
The information provided about the product on this Safety Data Sheet has been compiled from knowledge of the individual constituents The data given here is based on current knowledge and experience. This Safety Data Sheet describes the product in terms of safety requirements and does not signify any warranty with regard to the product's properties.The data given here only applies when product used for proper application(s). The productis not sold as suitable for other applications - usage in such may cause risks not mentioned in this sheet. Do not use for other application(s) without seeking advice from manufacturer.
DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.