Name: Alkaline Safety Liquid Plus
Brand: Fujairah Chemical
Availability: InStock

Part No: RXSOL-20-2005-026

Best suitable non caustic hold cleaner, which is suitable to clean when next cargo is food grain.

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Part No: RXSOL-20-2005-026

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Safety data (MSDS)

Porduct Name	Alkaline Safety Liquid Plus
Part Number	RXSOL-20-2005-026

Company Details:....

RX MARINE INTERNATIONAL
105, A wing , BSEL , TECH PARK.
VASHI ,NEW BOMBAY 400703 INDIA

Branch : Kandla, Mumbai , Chennai, Vizag, Kolkata, UAE , OMAN , CANADA and KENYA

Phone	+91 22 20871200 - 1400
Fax	+91 22 27612100 :::AOH :0091 9821214367
Email	mail@rxmarine.com
Website	www.rxmraine.com

Substances

Synonyms	3-Bromo-1-propene
Formula	C₃H₅Br
Molecular weight	120,98 g/mol
CAS-No.	106-95-6
EC-No.	203-446-6

Component	Classification	Concentration
3-bromo-1-propene
CAS-No. 106-95-6 EC-No 203-446-6 . Index-No. CAS-No. EC-No. Index-No.	Flam. Liq. 2; Acute Tox. 3; Skin Corr. 1B; Eye Dam. 1; Aquatic Acute 1; H225, H301, H331, H314, H318, H400 M-Factor - Aquatic Acute:10	= 100 %
propylene oxide Included in the Candidate List of Substances of Very High Concern (SVHC) according to Regulation (EC) No. 1907/2006 (REACH)
CAS-No. 75-56-9 EC-No. 200-879-2 Index-No. 603-055-00-4	Flam. Liq. 1; Acute Tox. 4; Acute Tox. 3; Eye Irrit. 2; Muta. 1B; Carc. 1B; STOT SE 3; H224, H302, H331, H311, H319, H340, H350, H335	>= 0,1 - 1 %

For the full text of the H-Statements mentioned in this Section, see Section 16.

Classification of the substance or mixture

Flammable liquids, (Category 2)	H225: Highly flammable liquid and vapor.
Eye irritation, (Category 2)	H319: Causes serious eye irritation.
Skin sensitization, (Category 1)	H317: May cause an allergic skin reaction.
Specific target organ toxicity - single exposure, (Category 3), Respiratory system	H335: May cause respiratory irritation.
Long-term (chronic) aquatic hazard, (Category 2)	H411: Toxic to aquatic life with long lasting effects.

Label elements

Hazard Statements H225 H317 H319 H335 H411	Highly flammable liquid and vapor May cause an allergic skin reaction. Causes serious eye irritation. May cause respiratory irritation. Toxic to aquatic life with long lasting effects.
Precautionary Statements P210 P233 P273 P280	Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. Keep container tightly closed. Avoid release to the environment. Wear protective gloves/ protective clothing/ eye protection/ face protection.
P303 + P361 + P353	IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water
P304 + P340 + P310	IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER/ doctor.
P305 + P351 + P338	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
Supplemental Hazard Statements	none
Other hazards	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher. Ecological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher. Toxicological information: The substance/mixture does not contain components considered to have endocrine disrupting properties according to REACH Article 57(f) or Commission Delegated regulation (EU) 2017/2100 or Commission Regulation (EU) 2018/605 at levels of 0.1% or higher.

Description of first aid measures

General advice	First aiders need to protect themselves. Show this material safety data sheet to the doctor in attendance.
If inhaled	After inhalation: fresh air. Immediately call in physician. If breathing stops: immediately apply artificial respiration, if necessary also oxygen.
In case of skin contact	In case of skin contact: Take off immediately all contaminated clothing. Rinse skin with water/ shower. Call a physician immediately.
In case of eye contact	After eye contact: rinse out with plenty of water. Immediately call in ophthalmologist. Remove contact lenses.
If swallowed	If swallowed: give water to drink (two glasses at most). Seek medical advice immediately. In exceptional cases only, if medical care is not available within one hour, induce vomiting (only in persons who are wide awake and fully conscious), administer activated charcoal (20 - 40 g in a 10% slurry) and consult a doctor as quickly as possible. Do not attempt to neutralise.
Most important symptoms and effects, both acute and delayed	The most important known symptoms and effects are described in the labelling (see section 2.2) and/or in section 11
Indication of any immediate medical attention and special treatment needed	No data available

Extinguishing media

Suitable extinguishing media	Water Foam Carbon dioxide (CO2) Dry powder
Unsuitable extinguishing media	For this substance/mixture no limitations of extinguishing agents are given.
Special hazards arising from the substance or mixture	Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Highly flammable liquid and vapor. Runoff to sewer may create fire or explosion hazard. In a fire or if heated, a pressure increase will occur and the container may burst, with the risk of a subsequent explosion. The vapor/gas is heavier than air and will spread along the ground. Vapors may accumulate in low or confined areas or travel a considerable distance to a source of ignition and flash back. Carbon oxides Hydrogen bromide gas Flash back possible over considerable distance., Container explosion may occur under fire conditions. Combustible. Pay attention to flashback. Vapors are heavier than air and may spread along floors. Development of hazardous combustion gases or vapours possible in the event of fire. Forms explosive mixtures with air at ambient temperatures.
Advice for firefighters	Stay in danger area only with self-contained breathing apparatus. Prevent skin contact by keeping a safe distance or by wearing suitable protective clothing.
Further information	Remove container from danger zone and cool with water. Suppress (knock down) gases/vapors/mists with a water spray jet. Prevent fire extinguishing water from contaminating surface water or the ground water system. spray to keep fire-exposed containers cool.Promptly isolate the scene by removing all persons from the vicinity of the incident if there is a fire. No action shall be taken involving any personal risk or without suitable training. Move containers from fire area if this can be done without risk. Use water spray to keep fire-exposed containers cool.

Personal precautions, protective equipment and emergency procedures	Advice for non-emergency personnel: Avoid inhalation of dusts. Avoid substance contact. Ensure adequate ventilation. Evacuate the danger area, observe emergency procedures, consult an expert. For personal protection see section 8.
Environmental precautions	Do not let product enter drains.
Methods and materials for containment and cleaning up	Cover drains. Collect, bind, and pump off spills. Observe possible material restrictions (see sections 7 and 10). Take up dry. Dispose of properly. Clean up affected area. Avoid generation of dusts.
Reference to other sections	For disposal see section 13.

Precautions for safe handling

Advice on safe handling	Work under hood. Do not inhale substance/mixture.
Hygiene measures	Immediately change contaminated clothing. Apply preventive skin protection. Wash hands and face after working with substance. For precautions see section 2.2.
Conditions for safe storage, including any incompatibilities Storage conditions	Tightly closed. Dry.
Storage class	Storage class (TRGS 510): 8A: Combustible, corrosive hazardous materials
Specific end use(s)	Apart from the uses mentioned in section 1.2 no other specific uses are stipulated

Control parameters

Ingredients with workplace control parameters

Exposure controls

Personal protective equipment

Eye/face protection	Use equipment for eye protection tested and approved under appropriate government standards such as NIOSH (US) or EN 166(EU). Tightly fitting safety goggles
Skin protection	This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Full contact Material: Chloroprene Minimum layer thickness: 0,65 mm Break through time: 480 min Material tested:KCL 720 Camapren® This recommendation applies only to the product stated in the safety data sheet, supplied by us and for the designated use. When dissolving in or mixing with other substances and under conditions deviating from those stated in EN 16523-1 please contact the supplier of CE-approved gloves (e.g. KCL GmbH, D-36124 Eichenzell, Internet: www.kcl.de). Splash contact Material: Latex gloves Minimum layer thickness: 0,6 mm Break through time: 60 min Material tested:Lapren® (KCL 706 / Aldrich Z677558, Size M).
Body Protection	Flame retardant antistatic protective clothing.
Respiratory protection	Recommended Filter type: Filter A-(P3) The entrepeneur has to ensure that maintenance, cleaning and testing of respiratory protective devices are carried out according to the instructions of the producer. These measures have to be properly documented.
Control of environmental exposure	Do not let product enter drains.

Physical state	liquid
Colour	No data available
Odor	No data available
Melting point/freezing point	Melting point/range: -119 °C
Initial boiling point and boiling range	70 - 71 °C
Flammability (solid, gas)	No data available
Upper/lower flammability or explosive limits	Upper explosion limit: 7,3 %(V) Lower explosion limit: 4,4 %(V)
Flash point	-1 °C - c.c.
Autoignition temperature	No data available
Decomposition temperature	No data available
pH	No data available materials.Extremely flammable in the presence of the following materials or conditions: oxidizing materials.
Viscosity	Viscosity, kinematic: No data available Viscosity, dynamic: No data available
Water solubility	ca.21,5 g/l at 25 °C - completely soluble
Partition coefficient: n-octanol/water	log Pow: 1,94 - Bioaccumulation is not expected.
Vapor pressure	0,147 hPa at 25 °C
Density	1,034 g/mL at 25 °C - lit.
Relative density	1,03 at 20 °C
Relative vapor density	No data available
Particle characteristics	No data available
Explosive properties	No data available
Oxidizing properties	None
Other safety information	Dissociation constant 10,26 at 25 °C

Reactivity	Vapors may form explosive mixture with air.
Chemical stability	The product is chemically stable under standard ambient conditions (room temperature) . Contains the following stabilizer(s): propylene oxide (=0,1 %)
Possibility of hazardous reactions	Violent reactions possible with: Exothermic reaction with: Oxidizing agents Alkali metals Alkaline earth metals Light metals amides Amines Powdered metals
Conditions to avoid	May polymerize on exposure to light. Exposure to moisture. Exposure to air. Warming.
Incompatible materials	No data available
Hazardous decomposition products	In the event of fire: see section 5

Information on toxicological effects

Acute toxicity	LD50 Oral - Rat - male - 207,0 mg/kg Remarks: Sense Organs and Special Senses (Nose, Eye, Ear, and Taste):Olfaction:Other changes. Behavioral:Convulsions or effect on seizure threshold. Gastrointestinal:Ulceration or bleeding from stomach. (ECHA) Symptoms: If ingested, severe burns of the mouth and throat, as well as a danger of perforation of the esophagus and the stomach. Acute toxicity estimate Oral - 207 mg/kg (ATE value derived from LD50/LC50 value) LC50 Inhalation - Rat - 1 h - > 710 mg/m3 Remarks: (RTECS) LD50 Dermal - Rabbit - 301,0 mg/kg Remarks: Behavioral:Tremor. Gastrointestinal:Changes in structure or function of salivary glands. Kidney, Ureter, Bladder:Other changes. (ECHA) Acute toxicity estimate Dermal - 301 mg/kg (ATE value derived from LD50/LC50 value)
Skin corrosion/irritation	Skin - Rabbit Result: Causes burns. Remarks: (ECHA)
sensitization	Not available
mutagenicity	Not available
Carcinogenicity	Not available
Reproductive toxicity	Not available
Teratogenicity	Not available
Specific target organ toxicity (single exposure)	Not available.
Specific target organ toxicity (repeated exposure)	Not available.
Aspiration hazard	Not available.
Information on the likely routes of exposure	Not available.

Persistence and degradability	No data available
Toxicity to fish	Static test LC50 - Oncorhynchus mykiss (rainbow trout) - 75 mg/l - 96 h (OECD Test Guideline 203)
Toxicity to daphnia and other aquatic invertebrates	Static test EC50 - Daphnia magna (Water flea) - 42,81 mg/l - 48 h (OECD Test Guideline 202) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Toxicity	Toxicity to fish LC50 - Pimephales promelas (fathead minnow) - 1.520 mg/l - 96 h
Toxicity to bacteria	EC10 - Bacteria - 14 mg/l - 72 h Remarks: (Lit.) EC5 - E.coli - 15.000 mg/l Remarks: (Lit.) (maximum permissible toxic concentration)
Toxicity to algae	Static test ErC50 - Pseudokirchneriella subcapitata (green algae) - 74,35 mg/l - 72 h (OECD Test Guideline 201) Remarks: (in analogy to similar products) The value is given in analogy to the following substances: maleic acid
Products Biodegradation	The methods for determining the biological degradability are not applicable to inorganic substances.
Mobility in soil	No data available
Results of PBT and vPvB assessment	This substance/mixture contains no components considered to be either persistent, bioaccumulative and toxic (PBT), or very persistent and very bioaccumulative (vPvB) at levels of 0.1% or higher.
Endocrine disrupting properties	No data available
Other adverse effects	No data available .

Product	Offer surplus and non-recyclable solutions to a licensed disposal company. Waste material must be disposed of in accordance with the Directive on waste 2008/98/EC as well as other national and local regulations. Leave chemicals in original containers. No mixing with other waste. Handle uncleaned containers like the product itself.
Contaminated packaging	Dispose of as unused product.
Waste treatment Method	See www.retrologistik.com for processes regarding the return of chemicals and containers, or contact us there if you have further questions.

UN number	ADR/RID:1099 IMDG:1099 IATA: 1099
UN proper shipping name	ADR/RID: ALLYL BROMIDE IMDG: ALLYL BROMIDE IATA: Allyl bromide Passenger Aircraft: Not permitted for transport
Transport hazard class(es)	ADR/RID: 3 (6.1) IMDG: 3 (6.1) IATA:3 (6.1)
Packaging group	ADR/RID: I IMDG: I IATA:I
Environmental hazards	ADR/RID: yes IMDG Marine pollutant: yes IATA: no
Special precautions for user Tunnel restriction code Further information	(C/E) No data available

Safety, health and environmental regulations/legislation specific for the substance or mixture	This material safety data sheet complies with the requirements of Regulation (EC) No. 1907/2006.
Other regulations	Observe work restrictions regarding maternity protection in accordance to Dir 92/85/EEC or stricter national regulations where applicable. Take note of Dir 94/33/EC on the protection of young people at work.
Chemical Safety Assessment	For this product a chemical safety assessment was not carried out

Other Information

The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and weassume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if Rx Marine International has been advised of the possibility of such damages.

DISCLAIMER OF LIABILITY :The information in this SDS was obtained from sources which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, this MSDS information may not be applicable.